The 5-cm-diameter double-sided YBa2Cu3O7 (YBCO) films were prepared by metal organic deposition (MOD) using a commercially available metal-naphthenate coating solution. Firstly, YBCO film was prepared by MOD on one side of a double-side-polished 5-cm-diameter LaAlO3 substrate. Secondly, another side was similarly coated with YBCO by MOD. After the latter processing, degradation of average Jc value in the first side was not observed; but the fluctuation of critical current density Jc slightly increased. The double-sided YBCO films showed average Jc values of 0.8-1.0 MA/cm2 at 77 K and microwave surface resistances Rs(12 GHz) of 0.86-1.07 mΩ at 70 K.