For mobile communication systems with code division multiple access (CDMA), a new modulation scheme, π/2-shift BPSK, is proposed. The performance has been evaluated in terms of relative out-of-band power, bit-error rate (BER), and spectral efficiency. As the result, it is shown that the proposed scheme has an advantage over conventional BPSK, conventional QPSK, and π/4-shift QPSK under nonlinear amplification.