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[Author] Masahiro HIRABARU(1hit)

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  • Plasmaless Dry Etching of Silicon Nitride Films with Chlorine Trifluoride Gas

    Yoji SAITO  Masahiro HIRABARU  Akira YOSHIDA  

     
    PAPER

      Vol:
    E75-C No:7
      Page(s):
    834-838

    Plasmaless etching using ClF3 gas has been investigated on nitride films with different composition. For the sputter deposited and thermally grown silicon nitride films containing no hydrogen, the etch rate increases and the activation energy decreases with increase of the composition ratio of silicon to nitrogen between 0.75 and 1.3. This fact indicates that the etching is likely to proceed through the reaction between Si and ClF3. The native oxide on the silicon-nitride films can also be removed with ClF3 gas. Ultra-violet light irradiation from a low pressure mercury lamp remarkably accelerates the removal of the native oxide and the etch rate of the thermally grown silicon-nitride films. For the plasma deposited films, the etch rate is strongly accelerate with increasing hydrogen content in the films, but the activation energy hardly depends on the bounded hydrogen in the films, consistent with the results for Si etching.