New good convolutional codes with optimal free distance are tabulated for the number of memories M 22 and rate R=1/2, which were selected based on the criterion of minimizing the decoding error rate and bit error rate. Furthermore, for R=1/3, 1/4 and M 13, we give the new good codes and make clear the existance of the codes with minimum free distance which achieve to Heller's upper bound for M 16.