Left-weight sequences (LW-sequences for short) are in common currency for encoding binary trees. In [16], Wu et al. proposed an algorithm associated with tree rotations for listing all binary trees in diverse representations including LW-sequences. In particular, such a list of LW-sequences is generated in Gray-code order. In this paper, based on this ordering, we present efficient ranking and unranking algorithms. For binary trees with n internal nodes, the time complexity and the space requirement in each of our ranking and unranking algorithms are O(n2) and O(n), respectively.