1-2hit |
Wen-Kai LIN Shui-Hsiang SU Cheng-Lin HUANG Meiso YOKOYAMA
In this study, flexible organic solar cells (OSCs) employing a solution-processed hole-transporting layer (HTL) and low temperature annealing active layer have been fabricated. Vanadium oxide (V$_{2}$O$_{5})$, poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), V$_{2}$O$_{5}$/PEDOT:PSS or PEDOT:PSS/V$_{2}$O$_{5}$ is used as the HTL. Poly(3-hexythiophene) (P3HT):[6,6]-phenyl C61-butyric acid methyl ester (PCBM) is used as the active layer. HTL and active layer are all formed by a spin coating method on polyethylene terephthalate (PET) substrates. The OSC configuration has been optimized in the study to be PET/ITO/V$_{2}$O$_{5}$/PEDOT:PSS/P3HT:PCBM/LiF/Al. Based on a low annealing temperature of 90$^{circ}$C for P3HT:PCBM and parameters optimization of solution-processed V$_{2}$O$_{5}$/PEDOT:PSS, the OSC demonstrates a current density (JSC) and power conversion efficiency (PCE) of 6.08, mA/cm$^{2}$ and 1.57%, while an OSC without the HTL has PCE around 0.06%. The V$_{2}$O$_{5}$/PEDOT:PSS stacked HTL provides not only a stepwise hole-transporting energy diagram configuration but a smooth film surface for coating P3HT:PCBM active layer, which subsequently increases charge carrier transporting capability and extracts holes from the active layer to the anode.
Meiso YOKOYAMA Chi-Shing LI Shui-Hsiang SU
This work presents a novel field emission organic light emitting diode (FEOLED), in which an inorganic phosphor thin film is replaced by an organic EL light-emitting layer in the configuration of a field emission display (FED). The field emission electrons emitted from the carbon nanotubes (CNTs) cathode of the proposed FEOLED intensify the electron density in the multi-layer organic materials of the OLED; thus, resulting a higher luminous efficiency than that of a conventional OLED. Additionally, the luminance of the proposed FEOLED can be further increased from 10,820 cd/m2 to 27,393 cd/m2 by raising the current density of OLED through an external electron source. A balanced quantity of electrons and holes in the OLED, which is achieved by the proposed FEOLED increases the number of excitons and attributes the enhancement of luminous efficiency of the OLED. Under the same operating current density, the proposed FEOLED exhibits a higher luminous efficiency than that of a conventional OLED.