Synchronization and chaos of the oscillator circuit that is composed of two Duffing-Rayleigh oscillators coupled by resistor are investigated. The characteristic feature of this system is that the cubic nonlinear restoring force of each oscillator. The restoring force causes the Neimark-Sacker bifurcation with various synchronizations in the parameter plane. We clarify the bifurcation structure related with this nonlinear phenomenon, and study the chaotic state and its bifurcation process. Especially, we deals with the case that the symmetrical property is broken by changing system parameters.