For improving the fifth-generation mobile communication system, a highly efficient power amplifier must be designed for the base station. An outphasing amplifier is expected to be a solution for achieving high efficiency. We designed a combiner, one of the key components of the outphasing amplifier, using a serial Chireix combiner and fabricated an amplifier with a GaN HEMT, achieving 70% or more high efficiency up to 9 dB back-off power in an 800 MHz band. We also fabricated a 2 GHz-band outphasing amplifier with the same design. We applied digital predistortion (DPD) to control the balance of amplifying units in this amplifier and achieved an average efficiency of 65% under a 20 MHz modulation bandwidth.