This letter studies the secrecy outage probability (SOP) and the secrecy diversity order of Alamouti STBC with decision feedback (DF) detection over the time-selective fading channels. For given temporal correlations, we have derived the exact SOPs and their asymptotic approximations for all possible combinations of detection schemes including joint maximum likehood (JML), zero-forcing (ZF), and DF at Bob and Eve. We reveal that the SOP is mainly influenced by the detection scheme of the legitimate receiver rather than eavesdropper and the achievable secrecy diversity order converges to two and one for JML only at Bob (i.e., JML-JML/ZF/DF) and for the other cases (i.e., ZF-JML/ZF/DF, DF-JML/ZF/DF), respectively. Here, p-q combination pair indicates that Bob and Eve adopt the detection method p ∈ {JML, ZF, DF} and q ∈ {JML, ZF, DF}, respectively.