Aiming at the problem of the deterioration of the contact performance caused by the wear debris generated during the fretting wear of the electrical connector, low-frequency fretting wear experiments were carried out on the contacts of electrical connectors, the accumulation and distribution of the wear debris were detected by the electrical capacitance tomography technology; the influence of fretting cycles, vibration direction, vibration frequency and vibration amplitude on the accumulation and distribution of wear debris were analyzed; the correlation between characteristic value of wear debris and contact resistance value was studied, and a performance degradation model based on the accumulation and distribution of wear debris was built. The results show that fretting wear and performance degradation are the most serious in axial vibration; the characteristic value of wear debris and contact resistance are positively correlated with the fretting cycles, vibration frequency and vibration amplitude; there is a strong correlation between the sum of characteristic value of wear debris and the contact resistance value; the prediction error of ABC-SVR model of fretting wear performance degradation of electrical connectors constructed by the characteristic value of wear debris is less than 6%. Therefore, the characteristic value of wear debris in contact subareas can quantitatively describe the degree of fretting wear and the process of performance degradation.