Radio signals show small characteristic differences between radio transmitters resulted from their idiosyncratic hardware properties. Based on the parameters estimation of transmitter imperfections, a novel radiometric identification method is presented in this letter. The fingerprint features of the radio are extracted from the mismatches of the modulator and the nonlinearity of the power amplifier, and used to train a support vector machine classifier to identify the class label of a new data. Experiments on real data sets demonstrate the validation of this method.