Communication systems operating in the millimeter-wave (mmWave) band have the potential to realize ultra-high throughput and ultra-low latency vehicle-to-vehicle (V2V) communications in 5G and beyond wireless networks. Moreover, because of the weak penetration nature of mmWave, one mmWave channel can be reused in all V2V links, which improves the spectrum efficiency. Although the outstanding performance of the mmWave above has been widely acknowledged, there are still some shortcomings. One of the unavoidable defects is multipath interference. Even though the direct interference link cannot penetrate vehicle bodies, other interference degrades the throughput of the mmWave V2V communication. In this paper, we focus on the multipath interference caused by signal reflections from roads and surroundings, where the interference strength varies in road scenarios. Firstly, we analyze the multipath channel models of mmWave V2V with relay in three typical road scenarios (single straight roads, horizontal curves, and slopes). Their interference differences are clarified. Based on the analysis, a novel method of ZigZag antenna configuration is proposed to guarantee the required data rate. Secondly, the performance of the proposed method is evaluated by simulation. It proves that the ZigZag antenna configuration with an optimal antenna height can significantly suppress the destructive interference, and ensure a throughput over 1Gbps comparing to the conventional antenna configuration at 60GHz band. Furthermore, the effectiveness of ZigZag antenna configuration is demonstrated on a single straight road by outdoor experiments.