This paper deals with a characteristic of the so-called effective boundary condition for a plane wave scattering from periodic surfaces with perfect conductivity. The perturbation solution with all orders is explicitly given under the effective boundary condition. It is newly found that such a perturbation solution satisfies the optical theorem under the exact boundary condition. A comparison between such a perturbation solution and a reference solution for the exact boundary condition by other methods is performed. Then, the validity of such a perturbation solution is concretely discussed.