Lead bromide-based perovskite organic-inorganic quantum-well films incorporated polycyclic aromatic chromophores into the organic layer (in other words, hybrid quantum-wells combined lead bromide semiconductor and organic semiconductors) were prepared by use of the spin-coating technique from the DMF solution in which PbBr2 and alkyl ammonium bromides which were linked polycyclic aromatics, pyrene, phenanthrene, and anthracene. When the pyrene-linked methyl ammonium bromide, which has a relatively small molecular cross-section with regard to the inorganic semiconductor plane, was employed, a lead bromide-based perovskite structure was successfully formed in the spin-coated films. When the phenanthrene-linked and anthracene-linked ammonium bromides, whose chromophore have large molecular cross-sections, were employed, lead bromide-based perovskite structures were not formed. However, the introduction of longer alkyl chains into the aromatics-linked ammonium bromides made it possible to form the perovskite structure.

In order to obtain the uniform film having well-defined lead halide-based layer perovskite structure, we proposed squeezed out method. It is found that the optimized condition with respect to docosylammonium bromide is revealed by employing hexadecylammonium bromide among tetradecylammonium bromide, hexadecylammonium bromide and octadecylammonium bromide.