In a DC 50 V/3.3 A circuit, the spatial distributions of the spectral intensities of breaking arcs near the cathode for silver contacts were measured on the contact surfaces of three different shapes: flat and spherical (1 mm radius and 2 mm radius) and the arc temperature and the metal-vapor quantity were calculated from the spectral intensities. The influence of the contact shape on the arc temperature and the metal-vapor quantity were also examined, as well as the arc tracks on the contact surfaces and the gain and loss of the contacts. Findings show the distributions of spectral intensities are non-symmetrical from the beginning to the extinction of the breaking arc for the flat contact: However, they are symmetrical in the latter half of the breaking in spite of the number of breaking arcs and the shape of contact surface for the spherical contact. The relationship between the area of the arc tracks on the cathode and the shape of contact surface is the same as the relationship between the existent areas of measured spectra and the shape of the contact surface. For the spherical contacts, the arc temperature and the metal-vapor quantity are affected a little by the radius of the curved of contact surface and the number of breaking arcs. However, the longer the arc duration, the higher the metal-vapor quantity is in the latter period of the breaking arc. For the flat contacts, the metal-vapor quantity is lower than those for the spherical contacts. The gain and loss of the contacts are less and the arc duration is shorter for the flat contact than for the spherical contact.