At the present time, as downsizing of connectors causes thin gold plated layer and low contact load, serious problem of degradation of contact resistance property is induced. For these contacts, corrosion of the contacts surface under environment and high temperature as soldering and reflow process should be existed. Oxidation of base metal atoms which are diffused from under layer and additives occurs. Contact resistance increases for both surface contamination and low contact load. In order to resolve these problems and wear of surface, application of contact lubricants is useful and effective. However, degradation of the lubricants under such reflow process as high temperature possibly occurs. Therefore, in this study, from view point of change of lubricant quality as viscosity, weight loss, polymerization, oxidation and molecular orientation were clarified. For increase in contact resistance, orientation of lubricant molecular acts as important factor was found. The other factors of the lubricant hardly does not effect on contact resistance.

Self-organized organic dye particles of micrometer and submicrometer size were prepared by utilizing a wetting/dewetting process of polar solvent on a hydrophilic glass substrate. The near-field scanning optical microscopy successfully identified near-field excited near-field fluorescence from single particles, however, the majority of the small particles with diameters around 2 µm or less did not show fluorescence under near-field observation. In contrast, far-field fluorescence, when excited by a polarized evanescent field, was observed, with the intensity depending on the excitation polarization, indicating that molecules' transition moment within dye particles was oriented parallel to the substrate surface. Single particle fluorescence spectrum consistently showed an identical sharp peak with a large redshift, indicating that the particles were composed of identical dye aggregates similar to J-aggregates. These observations suggest that the near-field at the probe tip was polarized parallel to the probe axis. Another observation, that molecules were oriented in a similar direction among adjacent particles, suggests that the dewetting process contributed to the alignment of the molecular orientation among adjacent particles, which further proves that the present specimen was formed by a self-organizing mechanism.