Synchronization between two fully stretching piecewise affine Markov maps in the usual master-slave configuration has been proven to be possible in some interesting 2-dimensional and 3-dimensional cases. Aim of this contribution is to make a further step in the study of this phenomenon by showing that, if the two systems synchronize, the probability of having a certain synchronization time is bounded from above by an exponentially vanishing distribution. This result gives some formal ground to the numerical evidence shown in [2].