The effect of sampling-pulse pedestals, generated by pulse compression, on the temporal resolution in electro-optic (EO) sampling is studied both theoretically and experimentally. Analysis is made on how the pedestals degrade a measurement bandwidth and a temporal waveform. Based on the analysis, a practical guideline on the suppression of pedestals is also given. Gain-switched laser diode (LD) pulses adiabatically soliton-compressed using a dispersion decreasing fiber are used to confirm the theoretical results, and are successfully applied to high-temporal-resolution (>100 GHz) EO sampling measurements.