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Keisuke KAWACHI Kazunari SHINBO Yasuo OHDAIRA Akira BABA Keizo KATO Futao KANEKO
A quartz-crystal-microbalance (QCM) and surface-plasmon-resonance (SPR) hybrid sensor was prepared, and the depositions of polymer electrolytes layer-by-layer (LbL) films were observed in situ. The estimated thicknesses obtained from the QCM method were different from those obtained from the SPR method. This was estimated to be caused by film swelling and water contained in the film.
Kazunari SHINBO Makoto IWASAKI Yasuo OHDAIRA Akira BABA Keizo KATO Futao KANEKO
Ridge optical waveguides (OWGs) of fluorinated polyimides were deposited on a quartz crystal microbalance (QCM), and a hybrid sensor employing the OWG spectroscopy and the QCM technique was prepared. A polyvinyl alcohol (PVA) film with CoCl2 was deposited on the OWG, and humidity sensing characteristics were investigated. White light was entered into the waveguide and the output light spectra was observed. The output light intensity markedly changed because of the chromism of CoCl2 by humidity sorption. During the output light measurement, the QCM frequency was monitored simultaneously. The humidity dependences of the QCM frequency and output light were also investigated in a range from 10% to 70%. Furthermore, the response to hydrofluoroether (HFE) was observed, and the change in the output light was hardly observed because CoCl2 does not exhibit chromism in HFE sorption.
Ayako OMURA Hirofumi SHIOZAKI Shigeo HARA Tohru KAWAMOTO Akihito GOTOH Masahito KURIHARA Masaomi SAKAMOTO Hisashi TANAKA
The insoluble Prussian-blue (PB) pigment becomes possible to disperse in aqueous solution by covering their surfaces with ferrocyanide anions. The thin film fabricated with these water-dispersible PB nanoparticles shows evident electrochromic color changes between +0.8 V to -0.4 V on an ITO substrate. The mass change of the thin film during an electrochemical reaction is measured by means of electrochemical quartz crystal microbalance (EQCM). According to the EQCM analysis, the filling rate of water-dispersible PB nanoparticles in the film is 37.7% as compared with an assumed perfect crystal PB film.
Junichi IDE Yukihiko NAKAMURA Takamichi NAKAMOTO Toyosaka MORIIZUMI
Since odor sensing system is required in many fields, we have developed the system using QCM (Quartz Crystal Microbalance) sensor array and neural-network pattern recognition. In the present study, the mixed sensing films of two kinds of liquid-phase materials were characterized. As a result, it was found that the variety of sensing films were obtained by mixing two kinds of liquid-phase materials. The relative remnant of sensing film after repeated exposures was examined, and mixed films of two kinds of liquid-phase materials were found stable for the sensing materials.
Junichi IDE Yukihiko NAKAMURA Takamichi NAKAMOTO Toyosaka MORIIZUMI
Since the development of odor sensing system is required in many fields, we have been developing the system using QCM (Quartz Crystal Microbalance, 10 MHz AT-cut) array and neural-network pattern recognition. Since it is important to obtain stable sensor responses, a sensing film of lipid blended with PVC (polyvinyl chloride) was studied here. First, we studied the stability of various sensing films e. g. , phospholipids, GC liquid stationary phase materials and others in odor sensing system. It was found that most of lipids were stable, while PEG 200, octadecane and DBP were not stable materials. Second, we studied to obtain a stable QCM sensor using a sensing film blended with PVC. 4 plasticizers blended with PVC were systematically characterized, analyzing the pattern of QCM sensor responses by multivariate analysis. It was found that the pattern of DOPP was very different from that of PVC. Thus, we adopted DOPP as plasticizer and the stable sensor response was obtained using a lipid film blended with both PVC and DOPP. Finally, we studied the influence of sensing film materials on the stability of QCM sensors. It was found that the loss of sensing film mass after many vapor exposures depended upon the molecular weight.