A novel temporal convolution network-gated recurrent unit (NTCN-GRU) algorithm is proposed for the greatest of constant false alarm rate (GO-CFAR) frequency hopping (FH) prediction, integrating GRU and Bayesian optimization (BO). GRU efficiently captures the semantic associations among long FH sequences, and mitigates the phenomenon of gradient vanishing or explosion. BO improves extracting data features by optimizing hyperparameters besides. Simulations demonstrate that the proposed algorithm effectively reduces the loss in the training process, greatly improves the FH prediction effect, and outperforms the existing FH sequence prediction model. The model runtime is also reduced by three-quarters compared with others FH sequence prediction models.