A transmission ellipsometric method without an aperture was recently developed to characterize the electro-optic (EO) performance of EO polymers. The method permits much simpler optical setup compared to the reflection method, and allows easy performance of the incident angle dependence measurements using a conventional glass substrate and uncollimated beam. This paper shows the usefulness of this method for a simple and reliable evaluation of the EO coefficient both for organic and inorganic EO materials, as well as analysis for uniaxial anisotropic materials.