Thin film of polyurethane having metal complex was prepared by vapor deposition polymerization of bis (5,8-dihydroxyquinoline) zinc (ZnHq2) and 4, 4'-diphenylmethane diisocyanate monomers. The film was applied for the electron-transporting emissive layer of the organic light emitting diode. The deposition-polymerized film was found to give higher quantum efficiency of luminescence than the ZnHq2 monomer film.