Improvement of output and lifetime is a problem for biofuel cells. A structure was adopted in which gelation mixed with agarose and fuel (fructose) was sandwiched by electrodes made of graphene-coated carbon fiber. The cathode surface not contacting the gel was exposed to air. In addition, the anode surface not contacting the gel was in contact with fuel liquid to prevent the gel from being dry. The power density of the fuel cell was improved by increasing oxygen supply from air and the lifetime was improved by maintaining wet gel, that is, the proposed structure was a hybrid type having advantages of both fuel gel and fuel liquid. The output increased almost up to that of just using fuel gel and did not decrease significantly over time. The maximum power density in the proposed system was approximately 74.0 µW/cm2, an enhancement of approximately 1.5 times that in the case of using liquid fuel. The power density after 24 h was approximately 46.1 µW/cm2, which was 62% of the initial value.

An enzymatic biofuel cell (BFC) that uses lactic acid in human sweat as fuel to generate electricity is an attractive power source for wearable devices. A BFC capable of generating electricity with human sweat has been developed. It comprised a flexible tattoo seal type battery with silver oxide vapor deposited on a flexible material and conductive carbon nanotubes printed on it. The anode and cathode in this battery were arranged in a plane (planar type). This work proposes a thin laminated enzymatic BFC by inserting a cellulose nanofiber (CNF) sheet between two electrodes to absorb human sweat (stack-type). Optimization of the anode and changing the arrangement of electrodes from planar to stack type improved the output and battery life. The stack type is 43.20μW / cm2 at 180mV, which is 1.25 times the maximum power density of the planar type.