In this paper, the effects of Bragg scattering on ultra-wideband (UWB) signal transmission from periodic surfaces are reported. First, the frequency dispersive property of Bragg scattering is theoretically and experimentally confirmed. Next, the transfer function of both specular path and Bragg scattering are extracted. Then direct sequence UWB (DS-UWB) transmission simulations are conducted by using a raised cosine pulse that occupied 3.1 to 10.6 GHz and a Gaussian pulse that occupied 8.75 to 9.25 GHz. Finally, the effects of Bragg scattering on UWB systems are discussed.