We investigated luminescent properties in combination of red emissive europium complex of tris(dibenzoylmethane)-mono(4,7-dimethylphenanthroline)europium(III) [Eu(dbm)3phen] and blue phosphorescent molecule of bis[(4,6-difluorophenyl)-pyridinato-N,C2'] (picolinate) iridium (III) (FIrpic) doped in poly(N-vinyl-carbazole) (PVK). A sharp red emission from Eu(dbm)3phen was observed in photoluminescence (PL) measurement, whereas, in the case of electroluminescence (EL), emission from FIrpic and Eu compound were observed. The difference of the PL and EL spectra indicates that different energy transfer processes between Eu(dbm)3phen and FIrpic are suggested.

The luminance of about 10,000 cd/m2 at an applied voltage of 9.2 V and the external emission efficiency 5.5 cd/A at an injection current density of 50 mA/cm2 have been obtained from an organic light emitting diode (OLED) using starburst molecule doped with 5,6,11,12-tetraphenylnaphthacene fabricated by wet-processing. We demonstrate that the OLEDs fabricated by wet-processing can be applied to fields of short range optical communication as the electro-optical conversion device for transmitting the signals of moving picture.

We have demonstrated improvement in the efficiency of TDAPB-based OLEDs. The external quantum efficiency of 8.2% and a power efficiency of 17.3 lm/W were achieved. The results suggest that using the starburst small-molecule TDAPB allows for easy fabrication and is effective for achieving high efficiencies in simple device structures.