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Daisuke BARADA Kiyonobu TAMURA Takashi FUKUDA Akira EMOTO Toyohiko YATAGAI
Optical anisotropy was induced in azobenzene copolymer film using linearly or elliptically polarized laser beams. The Jones matrix of the anisotropic film was calculated from the change in polarization of the probe light. Two eigenpolarization states were obtained from the matrix. These two eigenstates are useful as a polarization basis for a polarization-tunable component.
Kenji SAKAMOTO Kiyoaki USAMI Toru SASAKI Sukekatsu USHIODA
We have investigated the pretilt angle of liquid crystal (LC) molecules induced by photo-alignment films of polyimide (Azo-PI) containing azobenzene in the backbone structure. To generate finite pretilt angles, the Azo-PI film with inclined alignment of the backbone structure was prepared by a double light-exposure method. In this method the corresponding polyamic acid (Azo-PAA) film was first exposed to linearly polarized ultraviolet/visible (UV/VIS) light (LP-light) at normal incidence, and then oblique angle irradiation of unpolarized UV/VIS light (UP-light) was performed in the plane of incidence perpendicular to the polarization direction of the LP-light. Repeated photo-isomerization reactions of azobenzene induce the alignment of the Azo-PAA backbone structure. By thermally imidizing the photo-treated film we obtained a thermally and optically stable Azo-PI film. The orientational distribution of the Azo-PI backbone structure was determined by measuring the polarized infrared absorption spectra as a function of the sample rotation angle and the angle of incidence. The pretilt angle of LC molecules was determined by a crystal rotation method. We found that the average inclination angle of the Azo-PI backbone structure increased with the UP-light exposure. The pretilt angle of LC molecules, measured from the surface plane, also increased with the UP-light exposure. We succeeded in generating a pretilt angle of 3. The relation between the LC pretilt angle and the average inclination angle of the Azo-PI backbone structure is discussed.