IEICE TRANSACTIONS on Electronics
Pretilt Angle of Liquid Crystals Induced by Photo-Aligned Films of Polyimide Containing Azobenzene in the Backbone Structure
Summary :
We have investigated the pretilt angle of liquid crystal (LC) molecules induced by photo-alignment films of polyimide (Azo-PI) containing azobenzene in the backbone structure. To generate finite pretilt angles, the Azo-PI film with inclined alignment of the backbone structure was prepared by a double light-exposure method. In this method the corresponding polyamic acid (Azo-PAA) film was first exposed to linearly polarized ultraviolet/visible (UV/VIS) light (LP-light) at normal incidence, and then oblique angle irradiation of unpolarized UV/VIS light (UP-light) was performed in the plane of incidence perpendicular to the polarization direction of the LP-light. Repeated photo-isomerization reactions of azobenzene induce the alignment of the Azo-PAA backbone structure. By thermally imidizing the photo-treated film we obtained a thermally and optically stable Azo-PI film. The orientational distribution of the Azo-PI backbone structure was determined by measuring the polarized infrared absorption spectra as a function of the sample rotation angle and the angle of incidence. The pretilt angle of LC molecules was determined by a crystal rotation method. We found that the average inclination angle of the Azo-PI backbone structure increased with the UP-light exposure. The pretilt angle of LC molecules, measured from the surface plane, also increased with the UP-light exposure. We succeeded in generating a pretilt angle of 3
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- IEICE TRANSACTIONS on Electronics Vol.E87-C No.11 pp.1936-1942
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- 2004/11/01
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- Special Section INVITED PAPER (Special Section on Electronic Displays)
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Kenji SAKAMOTO, Kiyoaki USAMI, Toru SASAKI, Sukekatsu USHIODA, "Pretilt Angle of Liquid Crystals Induced by Photo-Aligned Films of Polyimide Containing Azobenzene in the Backbone Structure" in IEICE TRANSACTIONS on Electronics,
vol. E87-C, no. 11, pp. 1936-1942, November 2004, doi: .
Abstract: We have investigated the pretilt angle of liquid crystal (LC) molecules induced by photo-alignment films of polyimide (Azo-PI) containing azobenzene in the backbone structure. To generate finite pretilt angles, the Azo-PI film with inclined alignment of the backbone structure was prepared by a double light-exposure method. In this method the corresponding polyamic acid (Azo-PAA) film was first exposed to linearly polarized ultraviolet/visible (UV/VIS) light (LP-light) at normal incidence, and then oblique angle irradiation of unpolarized UV/VIS light (UP-light) was performed in the plane of incidence perpendicular to the polarization direction of the LP-light. Repeated photo-isomerization reactions of azobenzene induce the alignment of the Azo-PAA backbone structure. By thermally imidizing the photo-treated film we obtained a thermally and optically stable Azo-PI film. The orientational distribution of the Azo-PI backbone structure was determined by measuring the polarized infrared absorption spectra as a function of the sample rotation angle and the angle of incidence. The pretilt angle of LC molecules was determined by a crystal rotation method. We found that the average inclination angle of the Azo-PI backbone structure increased with the UP-light exposure. The pretilt angle of LC molecules, measured from the surface plane, also increased with the UP-light exposure. We succeeded in generating a pretilt angle of 3
URL: https://global.ieice.org/en_transactions/electronics/10.1587/e87-c_11_1936/_p
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@ARTICLE{e87-c_11_1936,
author={Kenji SAKAMOTO, Kiyoaki USAMI, Toru SASAKI, Sukekatsu USHIODA, },
journal={IEICE TRANSACTIONS on Electronics},
title={Pretilt Angle of Liquid Crystals Induced by Photo-Aligned Films of Polyimide Containing Azobenzene in the Backbone Structure},
year={2004},
volume={E87-C},
number={11},
pages={1936-1942},
abstract={We have investigated the pretilt angle of liquid crystal (LC) molecules induced by photo-alignment films of polyimide (Azo-PI) containing azobenzene in the backbone structure. To generate finite pretilt angles, the Azo-PI film with inclined alignment of the backbone structure was prepared by a double light-exposure method. In this method the corresponding polyamic acid (Azo-PAA) film was first exposed to linearly polarized ultraviolet/visible (UV/VIS) light (LP-light) at normal incidence, and then oblique angle irradiation of unpolarized UV/VIS light (UP-light) was performed in the plane of incidence perpendicular to the polarization direction of the LP-light. Repeated photo-isomerization reactions of azobenzene induce the alignment of the Azo-PAA backbone structure. By thermally imidizing the photo-treated film we obtained a thermally and optically stable Azo-PI film. The orientational distribution of the Azo-PI backbone structure was determined by measuring the polarized infrared absorption spectra as a function of the sample rotation angle and the angle of incidence. The pretilt angle of LC molecules was determined by a crystal rotation method. We found that the average inclination angle of the Azo-PI backbone structure increased with the UP-light exposure. The pretilt angle of LC molecules, measured from the surface plane, also increased with the UP-light exposure. We succeeded in generating a pretilt angle of 3
keywords={},
doi={},
ISSN={},
month={November},}
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TY - JOUR
TI - Pretilt Angle of Liquid Crystals Induced by Photo-Aligned Films of Polyimide Containing Azobenzene in the Backbone Structure
T2 - IEICE TRANSACTIONS on Electronics
SP - 1936
EP - 1942
AU - Kenji SAKAMOTO
AU - Kiyoaki USAMI
AU - Toru SASAKI
AU - Sukekatsu USHIODA
PY - 2004
DO -
JO - IEICE TRANSACTIONS on Electronics
SN -
VL - E87-C
IS - 11
JA - IEICE TRANSACTIONS on Electronics
Y1 - November 2004
AB - We have investigated the pretilt angle of liquid crystal (LC) molecules induced by photo-alignment films of polyimide (Azo-PI) containing azobenzene in the backbone structure. To generate finite pretilt angles, the Azo-PI film with inclined alignment of the backbone structure was prepared by a double light-exposure method. In this method the corresponding polyamic acid (Azo-PAA) film was first exposed to linearly polarized ultraviolet/visible (UV/VIS) light (LP-light) at normal incidence, and then oblique angle irradiation of unpolarized UV/VIS light (UP-light) was performed in the plane of incidence perpendicular to the polarization direction of the LP-light. Repeated photo-isomerization reactions of azobenzene induce the alignment of the Azo-PAA backbone structure. By thermally imidizing the photo-treated film we obtained a thermally and optically stable Azo-PI film. The orientational distribution of the Azo-PI backbone structure was determined by measuring the polarized infrared absorption spectra as a function of the sample rotation angle and the angle of incidence. The pretilt angle of LC molecules was determined by a crystal rotation method. We found that the average inclination angle of the Azo-PI backbone structure increased with the UP-light exposure. The pretilt angle of LC molecules, measured from the surface plane, also increased with the UP-light exposure. We succeeded in generating a pretilt angle of 3
ER -
English
