A Uniform Lying Helix (ULH) liquid crystal device (LCD) fabricated by utilizing the characteristics of shear flow alignment as well as dielectric anisotropy was demonstrated. Cholesteric liquid crystals with a short helical pitch can exhibit an electric field-induced tilt. These experimental results indicate that it is possible to realize a high-speed response flexible LCD using plastic substrates.

The authors describe a method to produce gold nanoparticle-dispersed liquid crystals by means of sputtering, and discuss how the presence of gold nanoparticles affect the electro-optic response of the host liquid crystal. The method exploits the fact that liquid crystals possess low vapor pressures which allow them to undergo the sputtering process, and the target material is sputtered directly on the liquid crystal in a reduced air pressure environment. The sample attained a red-brownish color after sputtering, but no aggregations were observed in the samples kept in the liquid crystal phase. Polarization optical microscopy of the sample placed in a conventional sandwich cell revealed that the phase transition behaviour is affected by the presence of the nanoparticles and that the onset of the nematic phase is observed in the form of bubble-like domains whereas in the pure sample the nematic phase appears after the passing of a phase transition front. Transmission electron microscopy confirmed the presence of single nano-sized particles that were dispersed without forming aggregates in the material. The electro-optic properties of the nanoparticle-dispersed liquid crystal was investigated by measuring the threshold voltage for a twisted-nematic cell. The threshold voltage was found to depend on the frequency of the applied rectangular voltage, and at frequencies higher than 200 Hz, the threshold became lower than the pure samples.

We have investigated the pretilt angle of liquid crystal (LC) molecules induced by photo-alignment films of polyimide (Azo-PI) containing azobenzene in the backbone structure. To generate finite pretilt angles, the Azo-PI film with inclined alignment of the backbone structure was prepared by a double light-exposure method. In this method the corresponding polyamic acid (Azo-PAA) film was first exposed to linearly polarized ultraviolet/visible (UV/VIS) light (LP-light) at normal incidence, and then oblique angle irradiation of unpolarized UV/VIS light (UP-light) was performed in the plane of incidence perpendicular to the polarization direction of the LP-light. Repeated photo-isomerization reactions of azobenzene induce the alignment of the Azo-PAA backbone structure. By thermally imidizing the photo-treated film we obtained a thermally and optically stable Azo-PI film. The orientational distribution of the Azo-PI backbone structure was determined by measuring the polarized infrared absorption spectra as a function of the sample rotation angle and the angle of incidence. The pretilt angle of LC molecules was determined by a crystal rotation method. We found that the average inclination angle of the Azo-PI backbone structure increased with the UP-light exposure. The pretilt angle of LC molecules, measured from the surface plane, also increased with the UP-light exposure. We succeeded in generating a pretilt angle of 3. The relation between the LC pretilt angle and the average inclination angle of the Azo-PI backbone structure is discussed.

A novel fabrication process and materials of LC layers have been developed for three layer LCDs. It is based on LC/resist composite that can be applied to patterning LC layers with high resolution by conventional photolithography processes. Using this process, we fabricated a 2" matrix panel of three GH-LC layers stacked on a substrate for the fist time.

We report recent progress in the development of Liquid Crystal(LC) materials for the TN-TFT and ECB-TFT technologies, which require LC materials with positive and negative dielectric anisotropy, respectively. Many kinds of new LC materials have been synthesized and have been evaluated based on their fundamental physical properties. We have succeeded in identifying new LC materials, and developing new LC mixtures based on those, so that the current typical requirements of TFT-LCDs e.g. fast switching times, low power consumption, good viewing angles and wide operation temperature ranges together with high reliability can be fulfilled.

Flurorinated liquid crystal compounds having fluorophenyl, difluorophenyl and trifluorophenyl moieties combined with ester linkages, 1,2-ethylenes and covalent bonds were prepared and checked for their physical properties i.e. mesophases, dielectric and optical anisotropy. viscosity, pretilt angle and threshold voltage. By introducing fluorine atom(s) into the molecules, optical anisotropy and threshold voltage decreased, though the nematic temperature range diminished. The investigated compounds were all chemically stable and by using the compounds nematic liquid crystalline mixtures having low threshold voltage, low viscosity, large optical anisotropy and wide nematic ranges which were suitable for AM-LCDs, could be obtained.