We report the growth of carbon nanofibers (CNFs) from carbon particles by chemical vapor deposition (CVD) with ultrasonic neblizer using ethanol as carbon source. Dense CNFs having diameters of several tens of nanometers have been successfully synthesized by the CVD without using any metal catalysts. The carbon particles formed from decompostion of fullerene were found to be suitable for the synthesis of CNFs. Details of the optimum conditions for producing CNFs and the expected growth mechanism are also described.

Carbon nanofibers (CNFs) were fabricated on graphite plates using "Ar+ ion sputtering method" in large amount at room temperature. The morphology of CNFs was controlled by a simultaneous carbon supply during ion sputtering. CNF-tipped cones were formed on graphite plate surfaces without carbon supply whereas those with a simultaneous carbon supply featured mainly needle-like protrusions of large size. The field electron emission (FE) properties, measured using parallel plate configurations in 10-4 Pa range, showed the threshold fields of 4.4 and 5.2 V/µm with a current density of 1 µA/cm2 for CNF-tipped cones and needle-like protrusion, respectively. Reliability test results indicated that CNF-tipped cones were more stable than needle-like protrusion. The morphological change after reliability test showed a so-called "self-regenerative" process and structure damage for CNF-tipped cones and needle-like protrusions, respectively.