We investigated the electrical properties of hole transport materials such as TPD, α-NPD and m-MTDATA using in-situ field effect measurement. TPD, α-NPD and m-MTDATA films showed p-type semiconducting properties, and their electrical parameters such as conductivity, carrier mobility and carrier concentration were obtained. We also examined the effect of the substrate temperature during vacuum deposition and the thermal treatment after deposition, on the electrical parameters of the films. Experimental results showed that conductivity and carrier mobility decreased as the substrate temperature increased over the glass transition temperature. These decreases in conductivity and carrier mobility as a result of thermal treatment appear to be strongly related to the degradation mechanism of organic electroluminescent devices.

The doping effect of acceptor molecule tetracyanoquinodimethane (TCNQ) and donor molecule tetramethyltetraselenafulvalene (TMTSF) in an organic semiconductor was investigated by field effect measurements in merocyanine (MC) films. The electrical conductivity and carrier concentration of TCNQ-doped MC films were increased compared with those of undoped MC film. An efficient doping effect was observed at the doping concentration of approximately 9%. The electrical conductivity, on the other hand, was decreased by doping of the donor molecule TMTSF in MC film. However, no inversion of the conduction type was obtained. Furthermore, the transport mechanism of TCNQ-doped MC film and undoped film was elucidated from the temperature dependence of electrical parameters. These results demonstrate that TCNQ and TMTSF molecules act as acceptor and donor impurities in MC film, respectively, and the doping of these molecules is effective to control the electrical properties of organic semiconductors.