Deposition of inclined anisotropy film for bit-patterned media was studied using an oblique incidence collimated sputtering. Pt underlayer increased the inclination angle of magnetic layer more than 5° on a Ta seed layer. Further increase of the angle was obtained by annealing Pt/Ru underlayer resulting an inclination angle of 9.4° for a Co-Cr15.5 film on the underlayer. The magnetic properties of the Co-Cr15.5 film with an inclined orientation was estimated comparing measured hysteresis loops with simulated ones, which indicated to have inclined magnetic anisotropy with an anisotropy field of about 4.5kOe and a deflection angle of the anisotropy about the same as that of the crystalline orientation.

Mn1-xZnxFe2O4 thin films with various Zn contents, 300 nm in thickness, were synthesized on glass substrates directly by electroless plating in aqueous solution at 90 without a heat treatment. With XRD, SEM, VSM, the crystallographic structure, morphology of the films and the macroscopic magnetic properties were characterized. The Mn-Zn ferrite films have a single phase spinel structure and well-crystallized columnar grains grow perpendicularly to the substrate. The change of the coercivity is not consistent with that of the bulk materials. As the Zn content in the films increases, the value of Hc decreases firstly, and then increases. At x=0.5, the minimum value of Hc is 3.7 kA/m and the value of Ms is 419.6 kA/m. The hyperfine magnetic fields, cation occupations and the distribution of the magnetic moments in film plane were studied by the conversion electron Mossbauer spectroscopy (CEMS).

Microstructures of CoCr-alloy thin film media were investigated by cross-sectional transmission electron microscopy focussing on the initial growth region of the magnetic layer grown on nonmagnetic underlayers. An introduction of nonmagnetic hcp-CoCrRu layer between an hcp-CoCrPt recording layer and an hcp- or a bcc-underlayer improved the crystallographic quality of the initial growth region. Sharp compositional distributions of alloying elements at the interfaces of a CoCrPt/CoCrRu/CrTi perpendicular medium and a CoCrPt/CoCrRu/CrTi longitudinal medium were respectively confirmed by electron energy loss spectroscopy employing a finely focussed electron beam. Coercivity and squareness of the thin film media increased by realizing good hetero-epitaxy between the nonmagnetic and the magnetic hcp-layers.

The magnetic properties and the structure of electroless-deposited NiFeB films were investigated in comparison with those of electrodeposited NiFe films. The electroless-deposited NiFeB film with 27at% Fe content had the lowest coercivity, H, as low as 0.5 Oe with a saturation magnetic flux density, Bs, of 1.0 T. The saturation magnetostriction, λ, and the uniaxial magnetic anisotropy, Hk, were 5.010-6 and 10 Oe, respectively, which were larger than those of the conventional, electrodeposited permalloy film. The permeability of as-deposited Ni70Fe27B3 film was 1000 at 1 MHz. In order to improve the permeability, the film was heated at 200 in a magnetic field applied in the hard-axis direction to decrease the Hk value, and the permeability became 2000 at 1 MHz. The crystal structure and grain size of NiFeB and NiFe films were investigated by XRD, THEED and TEM. Both films with low Hc had an fcc structure; the grain size of the NiFeB film was smaller than 10 nm, while that of the NiFe film was larger, approximately 20 nm. The results suggested that the electroless-deposited NiFeB film had a larger magnetic anisotropy than the electrodeposited NiFe film. Moreover, the films with Hc less than 10 Oe ded not show clear difference between their TEM bright images and THEED patterns.