We report the control of threshold voltage (Vth) for low voltage (5V) operation in OFET by using double gate dielectric layers composed of poly (vinyl cinnamate) and SiO2. We succeeded in realizing a driving voltage of -5V and Vth shift by c.a. 1.0V. And programmed Vth was almost unchanged for 104s, where the relative change of Vth remains more than 99%.

We examined single crystal growth of benzothienobenzothiophene-based organic semiconductors by solution coating method using liquid crystal and investigated its electrical characteristics. As the results, we revealed that the averaged mobility in the saturation region reached 2.08 cm2/Vs along crystalline b-axis, and 1.08 cm2/Vs along crystalline a-axis.

The novel ladder-shaped polydiacetylene with a terephthalamide linker in the molecular center, namely poly(TPh-bisDA) was synthesized by photo-polymerization. The characteristics of thin films of polymer were dependent upon a casting solvent, but no significant change of backbone conformation of the PDA was observed. Obtained film is expected to be applied to the semi-conducting materials for organic field effect transistors (OFET).