Photophysical properties of water-soluble porphyrin were studied in aqueous solutions with/without DNA and in DNA solid films. Ultrathin films were prepared from aqueous DNA solutions by a spin-coating method on glass or on gold nanoparticles (AuNPs). Remarkable enhancement of phosphorescence was observed for porphyrin immobilized in DNA films spin-coated on AuNPs, which was attributed to the electric field enhancement and the increased radiative rate by localized surface plasmon resonance of AuNPs.

We report on the enhancement of system detection efficiency in a superconducting nanowire single-photon detector (SNSPD) by applying the optical cavity structure. The nanowire was made using 4-nm-thick NbN thin films and covered with an SiO cavity and Au mirror designed for 1300-1600 nm wavelengths. The device is mounted into fiber-coupled packages, and installed in a practical multichannel system based on GM cryocoolers. System detection efficiency depends on the absorptance of cavity structure, and reached 28% and 40% at 1550 nm and 1310 nm wavelengths, respectively. These values were considerably higher than an SNSPD without optical cavity.

Indium-sulfide-oxide thin films have been successfully deposited on indium-tin-oxide-coated glass from an aqueous solution containing Na2S2O3 and In2(SO4)3 by electrochemical deposition using a periodic 2-step-pulse voltage. The films have been annealed in nitrogen atmosphere for an hour at different temperatures; namely, 100, 200, 300 and 400. Then, the as-deposited and annealed films were characterized structurally, morphologically and optically. X-ray photoelectron spectroscopy (XPS) study was performed in order to understand the chemical states of the oxygen involved in the film composition. The photosensitivity was observed by means of photoelectrochemical measurements, which confirmed that the as-deposited and annealed films showed n-type conduction. Moreover, a heterostructure solar cell that has indium sulfide as a buffer layer and tin sulfide as an absorber was fabricated and characterized.

A new paradigm in the design of optical coatings connected with an outstanding computational efficiency of modern design techniques is discussed. Several other topics including pre-production error analysis, monitoring of coating production, and computational manufacturing of optical coatings are considered.

Mn1-xZnxFe2O4 thin films with various Zn contents, 300 nm in thickness, were synthesized on glass substrates directly by electroless plating in aqueous solution at 90 without a heat treatment. With XRD, SEM, VSM, the crystallographic structure, morphology of the films and the macroscopic magnetic properties were characterized. The Mn-Zn ferrite films have a single phase spinel structure and well-crystallized columnar grains grow perpendicularly to the substrate. The change of the coercivity is not consistent with that of the bulk materials. As the Zn content in the films increases, the value of Hc decreases firstly, and then increases. At x=0.5, the minimum value of Hc is 3.7 kA/m and the value of Ms is 419.6 kA/m. The hyperfine magnetic fields, cation occupations and the distribution of the magnetic moments in film plane were studied by the conversion electron Mossbauer spectroscopy (CEMS).

The effect of a nonmagnetic hcp-underlayer on the epitaxial growth of CoCr19Pt10 magnetic layers on substrates of Al2O3(0001) single-crystal has been investigated. Thin films of (0001)-oriented single-crystal CoCr19Pt10 were obtained by employing non-magnetic underlayers of CoCr25Ru25 and CoCr25Ru25/Ti, while thin films of polycrystalline CoCr19Pt10 were grown after the deposition of underlayers of TiCr10 and CoCr40. The growth of thin film CoCr19Pt10 on a Ti(0001) underlayer was interpreted as quasi-hetero-epitaxial where the continuity of the lattice across the interface is disturbed while the overall crystallographic relationship between the two layers is maintained. A thin film of epitaxially grown CoCr19Pt10 has a compositional variation of a few percent across the film plane in terms of elements that forms the alloy.

We report some leading research on superconducting devices in Taiwan. Research includes thin films, Josephson junctions, junction arrays and resonators etc. In device physics characteristics of Josephson junctions, junction array, and SQUIDs are reported. Applications of SQUIDs include: (1) studies of brain activities (magnetoencenphalogram) using multichannel low Tc SQUIDs system; (2) detection of weak magnetic fields (magnetocardiogragh, etc. ) using high-Tc SQUIDs; (3) nondestructive evaluation (NDE) of deep flaws using high-Tc SQUIDs. Research projects in the future in our group are briefly reported.

Layered Multicomposites by Sequential Adsorption (LAMSA) is layer by layer approach for ultrathin film fabrication that has been applied to a variety of organic and inorganic materials. In this paper, we present our objectives and work on the fabrication and modification of display devices and sensors primarily using LAMSA techniques. The term supramolecular layer assembly denotes the selective incorporation of processing techniques, layer configuration and molecular ordering that is achieved within planar devices. The first application involves modifying a polymer light emitting diode (PLED) device fabricated using the ITO/MEH-PPV/Ca protocol with ultrathin polyaniline derivatives. The second example involves photoinduced alignment in a hybrid LC cell configuration using polarized light with azo dye/polyelectrolyte ultrathin films. A supramolecular concept on substrates for opto- bioelectronic sensor configurations is described.

Pb(ZrxTi1-x)O3 (PZT) thin films were prepared on various electrodes. When Ir system materials were used as electrodes, fatigue properties of PZT thin films were improved. Moreover, in the case of the PZT thin film on an Ir/IrO2 electrode, not only fatigue but imprint properties were clearly improved. We could find these improvements were caused by good barrier effect of IrO2 from secondary ion mass spectroscopy (SIMS) analysis. By applying these Ir system electrodes, we fabricated stacked capacitors on polycrystalline silicon (poly-Si) plugs. In spite of high temperature thermal processing, we found poly-Si plugs were ohmically connected with the bottom electrodes of the capacitors from hysteresis measurements and I-V characteristics, and could greatly expect them for practical use.

To improve the emission properties of blue-emitting phosphor layer, SrS:Ce, we evaluated CeN instead of conventional CeCl3 as a starting material. We evaluated the composition and the crystallinity of the thin films using RBS and XRD methods. We also evaluated luminescent properties of EL devices using SrS:Ce phosphor layer. From the results of RBS and XRD measurements, we found that the concentration of the oxygen impurity in SrS:Ce thin films was decreased and the crystallinity of SrS:Ce thin films was improved when CeN is used. These results mean that the degradation of SrS:Ce thin films can be prevented by the use CeN. The evaluation of luminescent properties, shows that the luminance of SrS:Ce EL device is increased by the use of CeN.

Co-Zr and Co-Zr-Ta amorphous films were prepared by the Kr sputtering method for use as the backlayers of Co-Cr perpendicular magnetic recording tape media. The effect of the addition of Ta to Co-Zr thin films was also investigated. Lower substrate temperature was required to prepare amorphous Co-Zr films with excellent soft magnetic properties. The relationships among Ta content X, magnetostriction constant λ and magnetic characteristics such as coercivity Hc and relative permeability µr were clarified. A method of evaluating λ of soft magnetic thin films deposited on polymer sheet substrate has been presented. Films with composition of (Co95.7Zr4.3) 100-X TaX at X of 10 at.% possessed sufficiency soft magnetic properties such as low Hc below 80 A/m and high µr above 600. Addition of Ta was effective in changing change the sign of λ from positive to negative. It was found that the negative magnetoelastic energy and the smaller λ caused the soft magnetism.

The barrier-layer was successfully fabricated for a preparation of tunneling junction using high Tc oxidesuperconductor such as Bi-Sr-Ca-Cu-O system. Bi2Sr2Ca2Cu3Ox films were used for both superconducting electrodes and the barrier was mainly Bi2Sr2CaCu2O and the rest that was formed by effects of de-calcium from the first sputtered (2223) film. The reaction of de-calcium occurred immersing it in carbonated water. The change of (2223) phase of BSCCO was confirmed with a comparison of the intensity of X-ray diffraction. The superconductive transition temperature of the junction is different from that of the single film (2223) which had no treatment with carbonated water. Zero-bias-currents through fabricated barrier are observed and the critical currents depend on temperature so far as measured temperature region of 79 K-72 K.

High Tc superconducting (SC) active antennas made from thin films were produced by the magnetron sputtering method. The SC active antennas are found to be good for detecting 50GHz electromagnetic waves. Furthermore, the improvement of the sensitivity of the SC active antennas is demonstrated with the use of a corner reflector.