Hole Transport Property of α-phenyl-4'-(diphenylamino)stilbene Single Crystal Prepared Based on Solubility and Supersolubility Curves
Summary :
We describe the preparation of an α-phenyl-4'-(diphenylamino)stilbene (TPA) single crystal and the evaluation of its hole transport property. Based on the characterization using optical microscopy, polarizing microscopy, and X-ray diffraction, a large-scale TPA single crystal of dimensions 7.0×0.9×0.8mm is successfully synthesized using a solution method based on the solubility and supersolubility curves of the TPA. Notably, the current in the long-axis direction is larger than those in the short-axis and thickness directions (i(long) > i(short) > i(thickness)), which reveals the anisotropic charge transfer of the TPA single crystal. The observed anisotropic conductivity is well explained by the orientation of the triphenylamine unit in the TPA single crystal. Furthermore, the activation energy of the long-axis direction in the TPA single crystal is lower than that of the short-axis in TPA and all the axes in the α-phenyl-4'-[bis(4-methylphenyl)amino]stilbene single crystal reported in our previous study.
- Publication
- IEICE TRANSACTIONS on Electronics Vol.E102-C No.2 pp.132-137
- Publication Date
- 2019/02/01
- Publicized
- Online ISSN
- 1745-1353
- DOI
- 10.1587/transele.2018OMP0006
- Type of Manuscript
- Special Section PAPER (Special Section on Recent Progress in Organic Molecular Electronics and Biotechnology)
- Category
Authors
Mitsuhiko KATAGIRI
Nagaoka University of Technology
Shofu MATSUDA
Nagaoka University of Technology
Norio NAGAYAMA
Nagaoka University of Technology,RICOH Company, Ltd.
Minoru UMEDA
Nagaoka University of Technology
Keyword
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Mitsuhiko KATAGIRI, Shofu MATSUDA, Norio NAGAYAMA, Minoru UMEDA, "Hole Transport Property of α-phenyl-4'-(diphenylamino)stilbene Single Crystal Prepared Based on Solubility and Supersolubility Curves" in IEICE TRANSACTIONS on Electronics,
vol. E102-C, no. 2, pp. 132-137, February 2019, doi: 10.1587/transele.2018OMP0006.
Abstract: We describe the preparation of an α-phenyl-4'-(diphenylamino)stilbene (TPA) single crystal and the evaluation of its hole transport property. Based on the characterization using optical microscopy, polarizing microscopy, and X-ray diffraction, a large-scale TPA single crystal of dimensions 7.0×0.9×0.8mm is successfully synthesized using a solution method based on the solubility and supersolubility curves of the TPA. Notably, the current in the long-axis direction is larger than those in the short-axis and thickness directions (i(long) > i(short) > i(thickness)), which reveals the anisotropic charge transfer of the TPA single crystal. The observed anisotropic conductivity is well explained by the orientation of the triphenylamine unit in the TPA single crystal. Furthermore, the activation energy of the long-axis direction in the TPA single crystal is lower than that of the short-axis in TPA and all the axes in the α-phenyl-4'-[bis(4-methylphenyl)amino]stilbene single crystal reported in our previous study.
URL: https://global.ieice.org/en_transactions/electronics/10.1587/transele.2018OMP0006/_p
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@ARTICLE{e102-c_2_132,
author={Mitsuhiko KATAGIRI, Shofu MATSUDA, Norio NAGAYAMA, Minoru UMEDA, },
journal={IEICE TRANSACTIONS on Electronics},
title={Hole Transport Property of α-phenyl-4'-(diphenylamino)stilbene Single Crystal Prepared Based on Solubility and Supersolubility Curves},
year={2019},
volume={E102-C},
number={2},
pages={132-137},
abstract={We describe the preparation of an α-phenyl-4'-(diphenylamino)stilbene (TPA) single crystal and the evaluation of its hole transport property. Based on the characterization using optical microscopy, polarizing microscopy, and X-ray diffraction, a large-scale TPA single crystal of dimensions 7.0×0.9×0.8mm is successfully synthesized using a solution method based on the solubility and supersolubility curves of the TPA. Notably, the current in the long-axis direction is larger than those in the short-axis and thickness directions (i(long) > i(short) > i(thickness)), which reveals the anisotropic charge transfer of the TPA single crystal. The observed anisotropic conductivity is well explained by the orientation of the triphenylamine unit in the TPA single crystal. Furthermore, the activation energy of the long-axis direction in the TPA single crystal is lower than that of the short-axis in TPA and all the axes in the α-phenyl-4'-[bis(4-methylphenyl)amino]stilbene single crystal reported in our previous study.},
keywords={},
doi={10.1587/transele.2018OMP0006},
ISSN={1745-1353},
month={February},}
Copy
TY - JOUR
TI - Hole Transport Property of α-phenyl-4'-(diphenylamino)stilbene Single Crystal Prepared Based on Solubility and Supersolubility Curves
T2 - IEICE TRANSACTIONS on Electronics
SP - 132
EP - 137
AU - Mitsuhiko KATAGIRI
AU - Shofu MATSUDA
AU - Norio NAGAYAMA
AU - Minoru UMEDA
PY - 2019
DO - 10.1587/transele.2018OMP0006
JO - IEICE TRANSACTIONS on Electronics
SN - 1745-1353
VL - E102-C
IS - 2
JA - IEICE TRANSACTIONS on Electronics
Y1 - February 2019
AB - We describe the preparation of an α-phenyl-4'-(diphenylamino)stilbene (TPA) single crystal and the evaluation of its hole transport property. Based on the characterization using optical microscopy, polarizing microscopy, and X-ray diffraction, a large-scale TPA single crystal of dimensions 7.0×0.9×0.8mm is successfully synthesized using a solution method based on the solubility and supersolubility curves of the TPA. Notably, the current in the long-axis direction is larger than those in the short-axis and thickness directions (i(long) > i(short) > i(thickness)), which reveals the anisotropic charge transfer of the TPA single crystal. The observed anisotropic conductivity is well explained by the orientation of the triphenylamine unit in the TPA single crystal. Furthermore, the activation energy of the long-axis direction in the TPA single crystal is lower than that of the short-axis in TPA and all the axes in the α-phenyl-4'-[bis(4-methylphenyl)amino]stilbene single crystal reported in our previous study.
ER -
English
