Thin films of vinyl derivatives of naphthalene diimide were prepared by electron-assisted vapor deposition. Monomer materials of N, N'-bis(allyl)-naphthalene diimide (Allyl-NDI) and N,N'-bis(p-vinyl-benzyl)-naphthalene diimide (Sty-NDI) were newly synthesized for this purpose. Uniform films were obtained by vapor-depositing these materials, whereas spin-coating yielded nonuniform films. IR analysis suggested that Sty-NDI can be polymerized upon vapor deposition. An insoluble film of Sty-NDI was obtained by the electron-assisted vapor deposition. On the other hand, Allyl-NDI had lower reactivity for polymerization. It was concluded that Sty-NDI is a promising material for preparing thin films of vinyl polymer having naphthalene diimide units.
Keisuke TOMIDA
Tokyo University of Agriculture and Technology
Hiroshi FUJITA
Niigata University
Satoshi USUI
Niigata University
Kuniaki TANAKA
Tokyo University of Agriculture and Technology
Hiroaki USUI
Tokyo University of Agriculture and Technology
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Keisuke TOMIDA, Hiroshi FUJITA, Satoshi USUI, Kuniaki TANAKA, Hiroaki USUI, "Vapor-Deposition Polymerization of Vinyl Polymer Thin Films of Naphthalene Diimide Derivatives" in IEICE TRANSACTIONS on Electronics,
vol. E100-C, no. 2, pp. 141-144, February 2017, doi: 10.1587/transele.E100.C.141.
Abstract: Thin films of vinyl derivatives of naphthalene diimide were prepared by electron-assisted vapor deposition. Monomer materials of N, N'-bis(allyl)-naphthalene diimide (Allyl-NDI) and N,N'-bis(p-vinyl-benzyl)-naphthalene diimide (Sty-NDI) were newly synthesized for this purpose. Uniform films were obtained by vapor-depositing these materials, whereas spin-coating yielded nonuniform films. IR analysis suggested that Sty-NDI can be polymerized upon vapor deposition. An insoluble film of Sty-NDI was obtained by the electron-assisted vapor deposition. On the other hand, Allyl-NDI had lower reactivity for polymerization. It was concluded that Sty-NDI is a promising material for preparing thin films of vinyl polymer having naphthalene diimide units.
URL: https://global.ieice.org/en_transactions/electronics/10.1587/transele.E100.C.141/_p
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@ARTICLE{e100-c_2_141,
author={Keisuke TOMIDA, Hiroshi FUJITA, Satoshi USUI, Kuniaki TANAKA, Hiroaki USUI, },
journal={IEICE TRANSACTIONS on Electronics},
title={Vapor-Deposition Polymerization of Vinyl Polymer Thin Films of Naphthalene Diimide Derivatives},
year={2017},
volume={E100-C},
number={2},
pages={141-144},
abstract={Thin films of vinyl derivatives of naphthalene diimide were prepared by electron-assisted vapor deposition. Monomer materials of N, N'-bis(allyl)-naphthalene diimide (Allyl-NDI) and N,N'-bis(p-vinyl-benzyl)-naphthalene diimide (Sty-NDI) were newly synthesized for this purpose. Uniform films were obtained by vapor-depositing these materials, whereas spin-coating yielded nonuniform films. IR analysis suggested that Sty-NDI can be polymerized upon vapor deposition. An insoluble film of Sty-NDI was obtained by the electron-assisted vapor deposition. On the other hand, Allyl-NDI had lower reactivity for polymerization. It was concluded that Sty-NDI is a promising material for preparing thin films of vinyl polymer having naphthalene diimide units.},
keywords={},
doi={10.1587/transele.E100.C.141},
ISSN={1745-1353},
month={February},}
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TY - JOUR
TI - Vapor-Deposition Polymerization of Vinyl Polymer Thin Films of Naphthalene Diimide Derivatives
T2 - IEICE TRANSACTIONS on Electronics
SP - 141
EP - 144
AU - Keisuke TOMIDA
AU - Hiroshi FUJITA
AU - Satoshi USUI
AU - Kuniaki TANAKA
AU - Hiroaki USUI
PY - 2017
DO - 10.1587/transele.E100.C.141
JO - IEICE TRANSACTIONS on Electronics
SN - 1745-1353
VL - E100-C
IS - 2
JA - IEICE TRANSACTIONS on Electronics
Y1 - February 2017
AB - Thin films of vinyl derivatives of naphthalene diimide were prepared by electron-assisted vapor deposition. Monomer materials of N, N'-bis(allyl)-naphthalene diimide (Allyl-NDI) and N,N'-bis(p-vinyl-benzyl)-naphthalene diimide (Sty-NDI) were newly synthesized for this purpose. Uniform films were obtained by vapor-depositing these materials, whereas spin-coating yielded nonuniform films. IR analysis suggested that Sty-NDI can be polymerized upon vapor deposition. An insoluble film of Sty-NDI was obtained by the electron-assisted vapor deposition. On the other hand, Allyl-NDI had lower reactivity for polymerization. It was concluded that Sty-NDI is a promising material for preparing thin films of vinyl polymer having naphthalene diimide units.
ER -