The influence of impurities in performs and of the drawing condition on the hydrogen-induced loss increase in the OH absorption band and the radiation-induced loss increase is investigated. The loss increase is much larger in fibers contaminated by sodium. Moreover, the loss increase in fibers with natural SiO2 clad, which is contaminated by alkali ions, increases with increasing maximum temperature in the drawing furnace and with decreasing drawing speed. By thermodynamically analyzing these results, the origin of the loss increase is identified as follows:
(1) The OH loss increase and the radiation-induced loss increase are ascribed to the same origin.
(2) The structural reorientation from GeO4 tetrahedrons to GeO6 groups thermally occurs in the drawing process, when the perform is contaminated by alkali ions.
(3) The loss increase is induced through the reaction of H2 and radiation with GeO6 groups.
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Hiroaki HANAFUSA, Yoshinori HIBINO, Hiroki ITOH, Fumio YAMAMOTO, "Origin of Loss Increase Induced by Hydrogen and Radiation for GeO2-Doped SiO2 Fibers" in IEICE TRANSACTIONS on transactions,
vol. E71-E, no. 2, pp. 167-173, February 1988, doi: .
Abstract: The influence of impurities in performs and of the drawing condition on the hydrogen-induced loss increase in the OH absorption band and the radiation-induced loss increase is investigated. The loss increase is much larger in fibers contaminated by sodium. Moreover, the loss increase in fibers with natural SiO2 clad, which is contaminated by alkali ions, increases with increasing maximum temperature in the drawing furnace and with decreasing drawing speed. By thermodynamically analyzing these results, the origin of the loss increase is identified as follows:
(1) The OH loss increase and the radiation-induced loss increase are ascribed to the same origin.
(2) The structural reorientation from GeO4 tetrahedrons to GeO6 groups thermally occurs in the drawing process, when the perform is contaminated by alkali ions.
(3) The loss increase is induced through the reaction of H2 and radiation with GeO6 groups.
URL: https://global.ieice.org/en_transactions/transactions/10.1587/e71-e_2_167/_p
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@ARTICLE{e71-e_2_167,
author={Hiroaki HANAFUSA, Yoshinori HIBINO, Hiroki ITOH, Fumio YAMAMOTO, },
journal={IEICE TRANSACTIONS on transactions},
title={Origin of Loss Increase Induced by Hydrogen and Radiation for GeO2-Doped SiO2 Fibers},
year={1988},
volume={E71-E},
number={2},
pages={167-173},
abstract={The influence of impurities in performs and of the drawing condition on the hydrogen-induced loss increase in the OH absorption band and the radiation-induced loss increase is investigated. The loss increase is much larger in fibers contaminated by sodium. Moreover, the loss increase in fibers with natural SiO2 clad, which is contaminated by alkali ions, increases with increasing maximum temperature in the drawing furnace and with decreasing drawing speed. By thermodynamically analyzing these results, the origin of the loss increase is identified as follows:
(1) The OH loss increase and the radiation-induced loss increase are ascribed to the same origin.
(2) The structural reorientation from GeO4 tetrahedrons to GeO6 groups thermally occurs in the drawing process, when the perform is contaminated by alkali ions.
(3) The loss increase is induced through the reaction of H2 and radiation with GeO6 groups.},
keywords={},
doi={},
ISSN={},
month={February},}
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TY - JOUR
TI - Origin of Loss Increase Induced by Hydrogen and Radiation for GeO2-Doped SiO2 Fibers
T2 - IEICE TRANSACTIONS on transactions
SP - 167
EP - 173
AU - Hiroaki HANAFUSA
AU - Yoshinori HIBINO
AU - Hiroki ITOH
AU - Fumio YAMAMOTO
PY - 1988
DO -
JO - IEICE TRANSACTIONS on transactions
SN -
VL - E71-E
IS - 2
JA - IEICE TRANSACTIONS on transactions
Y1 - February 1988
AB - The influence of impurities in performs and of the drawing condition on the hydrogen-induced loss increase in the OH absorption band and the radiation-induced loss increase is investigated. The loss increase is much larger in fibers contaminated by sodium. Moreover, the loss increase in fibers with natural SiO2 clad, which is contaminated by alkali ions, increases with increasing maximum temperature in the drawing furnace and with decreasing drawing speed. By thermodynamically analyzing these results, the origin of the loss increase is identified as follows:
(1) The OH loss increase and the radiation-induced loss increase are ascribed to the same origin.
(2) The structural reorientation from GeO4 tetrahedrons to GeO6 groups thermally occurs in the drawing process, when the perform is contaminated by alkali ions.
(3) The loss increase is induced through the reaction of H2 and radiation with GeO6 groups.
ER -