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[Author] Hideo YOSHIHARA(1hit)

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  • Tantalum Dry-Etching Characteristics for X-Ray Mask Fabrication

    Akira OZAWA  Shigehisa OHKI  Masatoshi ODA  Hideo YOSHIHARA  

     
    PAPER-Integrated Electronics

      Vol:
    E77-C No:2
      Page(s):
    255-262

    Directional dry etching of Tantalum is described X-ray lithography absorber patterns. Experiments are carried out using both reactive ion etching in CBrF3-based plasma and electron-cyclotron-resonance ion-stream etching in Cl2-based plasma. Ta absorber patterns with perpendicular sidewalls cannot be obtained by RIE when only CBrF3 gas is used as the etchant. While adding CH4 to CBrF3 effectively improves the undercutting of Ta patterns, it deteriorates etching stability because of the intensive deposition effect of CH4 fractions. By adding an Ar/CH4 mixture gas to CBrF3, it is possible to use RIE to fabricate 0.2-µm Ta absorber patterns with perpendicular sidewalls. ECR ion-stream etching is investigated to obtain high etching selectivity between Ta and SiO2 (etching mask)/SiN (membrane). Adding O2 to the Cl2 etchant improves undercutting without remarkably decreasing etching selectivity. Furthermore, an ECR ion-stream etching method is developed to stably etch Ta absorber patterns finer than 0.2µm. This is successfully applied to X-ray lithography mask fabrication for LSI test devices.