Ultra shallow low-resistive junction formation has been investigated for sub-100-nm MOSFETs using antimony implantation. The pileup at the Si/SiO2 interface and the resulting dopant loss during annealing is a common obstacle for antimony and arsenic to reduce junction sheet resistance. Though implanted arsenic gives rise to pileup even with a few seconds duration RTA (Rapid Thermal Annealing), antimony pileup was suppressed with the RTA at relatively low temperature, such as 800 or 900. As a result, low sheet resistance of 260 Ω/sq. was obtained for a 24 nm depth junction with antimony. These results indicate that antimony is superior to arsenic as a dopant for ultra shallow extension formation. However, increase in antimony concentration above 11020 cm-3 gives rise to precipitation and it limits the sheet resistance reduction of the antimony doped junctions. Redistribution behaviors of antimony relating to the pileup and the precipitation are discussed utilizing SIMS (Secondary Ion Mass Spectrometry) depth profiles.

In recent years, ion implantation has become one of the key techniques in semiconductor fabrication. The annealing of the damage produced during implantation is, however, not fully understood. Ion implantation at high temperatures allows the time-resolved study of implantation-enhanced diffusion. During the process, point defects are generated by the ion implantation and consumed by recombination in the bulk as well as by diffusion to the surface and recombination there. With increasing temperatures, the recombination of point defects, which are acting as diffusion vehicles, results in reduced effective diffusion. Profiles processed above 900 show marked uphill diffusion at the surface caused by large gradients of the point defect concentrations. This uphill diffusion affirms the generally accepted pair diffusion theories. Since the point defects are in steady state even after process times which are short compared to the total process time, we are able to give a qualitative analysis of the dose dependence of the diffusion. By extensive numerical simulations, we could estimate the product of bulk recombination rate and equilibrium concentrations of self-interstitials and vacancies as well as the interface recombination velocity for the self-interstitials. The results obtained are in qualitative agreement with previous work of others. The results demonstrate, in fact, clearly the advantages of the method presented. But due to experimental problems concerning the temperature measurement, which have not been fully resolved up to now, the results have to be considered as crude estimates.