1-8hit |
Yuya TANAKA Yuki TAZO Hisao ISHII
In vacuum-deposited film composed of organic polar molecules, polarization charges appear on the film surface owing to spontaneous orientation of the molecule. Because its density (σpol) determines an amount of accumulation charge (σacc) in organic light-emitting diodes and output power in polar molecular-based vibrational energy generators (VEGs), control of molecular orientation is highly required. Recently, several groups have reported that dipole-dipole interaction between polar molecules induces anti-parallel orientation which does not contribute to σpol. In other words, perturbation inducing the attenuation of the dipole interaction is needed to enhance σpol. In this study, to investigate an effect of light irradiation on σpol, we prepared 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene (TPBi) film under illumination during its deposition, and evaluated the σacc in TPBi-based bilayer device, which equals to σpol. We found that the σacc was increased by light irradiation, indicating that average orientation of TPBi is enhanced. These results suggest that light irradiation during device fabrication is promising process for organic electronic devices including polar molecule-based VEGs.
Cuong Manh TRAN Tatsuya MURAKAMI Heisuke SAKAI Hideyuki MURATA
We demonstrate the effect of vacuum pressure on the mobility (µ) and the threshold voltage (Vth) of organic field effect transistor (OFETs) using copper as source-drain electrodes. OFETs with copper electrodes deposited at high background pressure are better in electric characteristics compared with traditional devices fabricated under low pressure using gold electrodes.
Masakazu MUROYAMA Ayako TAJIRI Kyoko ICHIDA Seiji YOKOKURA Kuniaki TANAKA Eiji OTSUKI Hiroaki USUI
Thin films of a divinyl derivative of tetraphenyldiaminobiphenyl DvTPD were prepared by vapor deposition followed by annealing. After annealing at 200°C for 1 h, the film became practically insoluble to organic solvents due to polymerization. Electrical characteristics of the films were measured by current-voltage measurement, time-of-flight measurement, and dielectric measurement. It was found that the hole mobility of DvTPD decreases when the film is polymerized. As a consequence of the decrease of hole mobility, carrier balance in the emissive layer of an organic light emitting diode (OLED) was improved, leading to a higher quantum efficiency and a pure emission spectrum. The dielectric measurement also confirmed the high thermal stability of the polymerized film.
Xiaodong WANG Kenji OGINO Kuniaki TANAKA Hiroaki USUI
Thin film of polyurethane having metal complex was prepared by vapor deposition polymerization of bis (5,8-dihydroxyquinoline) zinc (ZnHq2) and 4, 4'-diphenylmethane diisocyanate monomers. The film was applied for the electron-transporting emissive layer of the organic light emitting diode. The deposition-polymerized film was found to give higher quantum efficiency of luminescence than the ZnHq2 monomer film.
Hiroyuki FUJII Hiroshi KANNO Takeshi SANO Yoshitaka NISHIO Yuji HAMADA Hisakazu TAKAHASHI Tatsuro USUKI Kenichi SHIBATA
In order to improve the running durability of organic electroluminescent devices (OELDs), the doping sites of molecular OELDs were optimized, and the frequency responses of the optimized devices were examined for Mg-In/bis (10-hydroxybenzo[h]quinolinate) beryllium (BeBq2)/N, N'-diphenyl-N, N'-(3-methylphenyl)-1, 1'-biphenyl-4, 4'-diamine (TPD)/4, 4', 4"-tris (3-methylphenylphenylamino) triphenylamine (MTDATA)/ITO. The TPD hole transport layer was the optimum doping site for 5, 6, 11, 12-tetraphenylnaphthacene (rubrene) dopant, and a very high efficiency of 13 cd/A at 0. 13 kcd/m2 was obtained for yellow emission. Half-decay times under a constant direct current density of 1. 0 mA/cm2 from an initial luminance of 0. 13 kcd/m2 extended to longer than 26,000 hours. The luminance of the optimized device decreases lineally with respect to the logarithm of the frequency as the frequency increases in the range from 1 kHz to 0. 3 MHz when a square wave with a duty ratio of 50% and a maximum voltage of 5.0 V is applied. A new driving method involving frequency modulation is proposed. This may offer accurate control of pixel luminance, and enable simple driving circuits adapted to highly integrated digital LSI chips, or the concept of system on glass.
Yutaka OHMORI Norio TADA Yoshitaka KUROSAKA Hiroshi UETA Takumi SAWATANI Akihiko FUJII Katsumi YOSHINO
Multicolor light emitting diodes (LEDs) which emit red (R), green (G) and blue (B) light have been realized by stacking a two-color emission part on a single-color emission part. The former part consists of two emissive layers of red and blue light, which can be selected by changing the polarity of applied field. The latter part consists of a single-color emission part which emits green light. The emission from the diode in the whole visible spectral range can be modulated by the combination of applying various voltages to the two-color and to the single-color emission parts, separately.
To improve the emission properties of blue-emitting phosphor layer, SrS:Ce, we evaluated CeN instead of conventional CeCl3 as a starting material. We evaluated the composition and the crystallinity of the thin films using RBS and XRD methods. We also evaluated luminescent properties of EL devices using SrS:Ce phosphor layer. From the results of RBS and XRD measurements, we found that the concentration of the oxygen impurity in SrS:Ce thin films was decreased and the crystallinity of SrS:Ce thin films was improved when CeN is used. These results mean that the degradation of SrS:Ce thin films can be prevented by the use CeN. The evaluation of luminescent properties, shows that the luminance of SrS:Ce EL device is increased by the use of CeN.
Yutaka OHMORI Chikayoshi MORISHIMA Akihiko FUJII Katsumi YOSHINO
Electrical and optical properties of organic multilayer structure have been investigated. Two types of current-voltage characteristics have been found for thin multilayer structure of organic films. Optical property and its application for electroluminescent diode have been presented. The diode characteristics have been discussed in terms of energy band scheme.