Poled polymer films doped with novel nonlinear organic materials, α-cyano unsaturated carboxylic acid (α-CUCA) derivatives, are prepared. Linear and second-order nonlinear optical properties are investigated. It is found that as the value of hyperpolarizability of the derivatives increases, the second-order nonlinear susceptibility of the film increases. Cerenkov-type second harmonic generation (SHG) of Nd: YAG laser is realized in a poled polymer waveguide doped with the α-CUCA material with a slight absorption at doubled wavelength.

This paper theoretically evaluates the external electro-optic (EO) sampling of high-speed electrical signals using poled polymers as materials for a proximity electric-field sensor. Based on the derivation of the half-wave voltage and the analysis of a static electric field coupled to the polymeric media placed over IC interconnections, invasiveness, voltage sensitivity, and spatial resolution have been discussed. The polymeric sensors have shown to be used in contact with the IC interconnections with negligibly small invasiveness, thus making polymeric sensors provide higher sensitivity and spatial resolution than inorganic crystals such as GaAs and KD*P.

This letter describes damages of piezoelectric polymer using in hydrophones to measure high acoustic pressures at the focal point of Extracorporeal Shockwave Lithotripter (ESWL).

The nonlinear optical properties of organics with unsaturated bonds were compared with those of inorganics including semiconductors and dielectrics. Because of the mesomeric effect, namely quantum mechanical resonance effect among configurations, aromatic molecules and polymers have larger optical nonlinear parameters defined as δ(n)=X(n)/(X(l))n both for the second (n=2) and third-order (n=3) nonlinearities. Experimental results of ultrafast nonlinear response of conjugated polymers, especially polydiacetylenes, were described and a model is proposed to explain the relaxation processes of photoexcitations in the conjugated polymers. Applying the model constructed on the basis of the extensive experimental study, we propose model polymers to obtain ultrafast resonant optical nonlinearity.

The nonlinear optical properties of organics with unsaturated bonds were compared with those of inorganics including semiconductors and dielectrics. Because of the mesomeric effect, namely quantum mechanical resonance effect among configurations, aromatic molecules and polymers have larger optical nonlinear parameters defined as δ(n)X(n)/(X(1))n both for the second (n2) and third-order (n3) nonlinearities. Experimental results of ultrafast nonlinear response of conjugated polymers, especially polydiacetylenes, were described and a model is proposed to explain the relaxation processes of photoexcitations in the conjugated polymers. Applying the model constructed on the basis of the extensive experimental study, we propose model polymers to obtain ultrafast resonant optical nonlinearity.