Thin films of Teflon AF 1600 were prepared by an electron-assisted (e-assist) deposition method. IR analysis revealed that the e-assist deposition generates small amount of polar groups such as carboxylic acid in the molecular structure of the deposited films. The polar groups contributed to increase intermolecular interaction and led to remarkable improvement in the adhesion strength and robustness of the films especially when a bias voltage was applied to the substrate in the course of e-assist deposition. The vapor-deposited Teflon AF films had refractive indices of 1.35 to 1.38, and were effective for antireflection coatings. The use of e-assist deposition slightly increased the refractive index as a trade-off for the improvement of film robustness.

We investigated the photochemical stability of an electro-optic (EO) polymer under laser irradiation at 1310nm to reveal photodegradation mechanisms. It was found that one-photon absorption excitation assisted with the thermal energy at the temperature is involved in the photodegradation process, in contrast to our previous studies at a wavelength of 1550nm where two-photon absorption excitation is involved in the photodegradation process. Thus, both the excitation wavelength and the thermal energy strongly affect to the degradation mechanism. In any cases, the photodegradation of EO polymers is mainly related to the generation of exited singlet oxygen.

An electroactive supercoiled polymer artificial muscle, which is made from a conductive sewing thread using self-coiling caused by inserting a twist with a hanged appropriate weight, is 1/4-1/3 of the thread in length. Therefore, it is necessary to move the weight vertically about two or three times as long as the desired electroactive supercoiled polymer artificial muscle, resulting in a large vertical dimension of the fabrication equipment. This study has attempted to solve this problem by using constant-load springs that enable horizontal table-top fabrication equipment. It has been also demonstrated that inserting a twist into the bundled threads results in a strong electroactive supercoiled polymer artificial muscle.

This paper presents a simulation study on the printing behavior of three different EUV resist systems. Stochastic models for negative metal-based resist and conventional chemically amplified resist (CAR) were calibrated and then validated. As for negative-tone development (NTD) CAR, we commenced from a positive-tone development (PTD) CAR calibrated (material) and NTD development models, since state-of-the-art measurements are not available. A conceptual study between PTD CAR and NTD CAR shows that the stochastic inhibitor fluctuation differs for PTD CAR: the inhibitor level exhibits small fluctuation (Mack development). For NTD CAR, the inhibitor fluctuation depends on the NTD type, which is defined by categorizing the difference between the NTD and PTD development thresholds. Respective NTD types have different inhibitor concentration level. Moreover, contact hole printing between negative metal-based and NTD CAR was compared to clarify the stochastic process window (PW) for tone reversed mask. For latter comparison, the aerial image (AI) and secondary electron effect are comparable. Finally, the local CD uniformity (LCDU) for the same 20 nm size, 40 nm pitch contact hole was compared among the three different resists. Dose-dependent behavior of LCDU and stochastic PW for NTD were different for the PTD CAR and metal-based resist. For NTD CAR, small inhibitor level and large inhibitor fluctuation around the development threshold were observed, causing LCDU increase, which is specific to the inverse Mack development resist.

We previously developed a new terahertz (THz) wave detection method that utilizes the effect of nonlinear optical (NLO) polymers. The new method provided us with a gapless detection, a wide detection bandwidth, and a simpler optical geometry in the THz wave detection. In this paper, polarization dependences in THz wave detection by the Stark effect were investigated. The projection model was employed to analyze the polarization dependences and the consistency with experiments was observed qualitatively, surely supporting the use of the first-order Stark effect in this method. The relations between THz wave detection by the Stark effect and Stark spectroscopy or electroabsorption spectroscopy are also discussed.

It is found that the electrical resistance-length characteristic in an electroactive supercoiled polymer artificial muscle strongly depends on the temperature. This may come from the thermal expansion of coils in the artificial muscle, which increases the contact area of neighboring coils and results in a lower electrical resistance at a higher temperature. On the other hand, the electrical resistance-length characteristic collected during electrical driving seriously deviates from those collected at constant temperatures. Inhomogeneous heating during electrical driving seems to be a key for the deviation.

Temperature-independent zero-zero-birefringence polymer (TIZZBP), which exhibits very small birefringence over the wide temperature range, is required to realize real-color images for displays, particularly vehicle-mounted displays. Previously, a TIZZBP was synthesized, but they did not put into practical use because of their too complex composition and low mechanical strength. In this paper, we propose a practical TIZZBP that has high heat resistance, high transparency and sufficient mechanical strength, using a simple binary copolymerization system. Our proposed novel polymer exhibits very low photoelastic birefringence and very low orientational birefringence. Both types of birefringence of this TIZZBP satisfy the negligible levels for displays, which are defined as follows: the absolute values of photoelastic coefficient and intrinsic birefringence are less than 1 ×10-12 Pa-1 and 1 ×10-3, respectively. In addition, temperature dependency of orientational birefringence was very low. Orientational birefringence satisfies the negligible level all over the temperature range from around -40°C to 85°C. This temperature range is important because it is the operational temperature range for vehicle-mounted display. Furthermore, our proposed novel TIZZBP showed high heat resistance, high transparency and sufficient mechanical strength. The glass transition temperature was 194°C. The total light transmittance and the haze value is more than 91% and less than 1%, respectively. The tensile strength of non-oriented films was 35 ~ 50 MPa. These results suggest our proposed novel TIZZBP has high practicality in addition to very low birefringence. Therefore, this TIZZBP film will be very useful for various displays including vehicle-mounted displays and flexible displays.

S-shaped nonlinearity is found in the electrical resistance-length relationship in an electroactive supercoiled polymer artificial muscle. The modulation of the electrical resistance is mainly caused by the change in the contact condition of coils in the artificial muscle upon deformation. A mathematical model based on logistic function fairly reproduces the experimental data of electrical resistance-length relationship.

Copper (Cu) electroless plating was conducted on planar and microstructured polydimethylsiloxane (PDMS) substrates. In this study, organic thin films terminated with nitrogen (N)-containing groups, e.g. poly (dimethylaminoethyl methacrylate) brush (PDMAEMA), aminopropyl trimethoxysilane monolayer (APTES), and polydopamine (PDA) were used to anchor palladium (Pd) catalyst. While electroless plating was successfully promoted on all sample surfaces, PDMAEMA was found to achieve the best adhesion strength to the PDMS surfaces, compared to APTES- and PDA-covered PDMS substrates, due to covalent bonding, anchoring effects of polymer chains as well as high affinity of N atoms to Pd species. Our process was also successfully applied to the electroless plating of microstructured PDMS substrates.

Technological developments in direction control of axonal outgrowth are a must for advances in regenerative medicine of the nervous system. In order to solve the problem, we fabricate a new neural cell culture sheet by applying the soft lithography technique to micro-patterning of the extracellular matrix and using thin-film biodegradable polymer for the scaffold. Micro-trenches were coated with Dulbecco's phosphate-buffered saline (-) containing laminin, using micro-molding in capillaries (MIMIC), a soft lithography technique. Biodegradable thin films with micro-trenches were fabricated by UV-curing a polyanhydride solution covering the negative SU-8 mold through thiol-ene polymerization. Both approaches were performed conveniently, rapidly, and accurately. It is thought that these techniques are excellent in terms of convenience and high speed, and can contribute greatly to regenerative medicine.

Recently, a control technique of light distribution pattern has become important to improve the functionality and the light utilization efficiency of electronic displays, illumination devices and so on. As a light control technique, polymer-dispersed liquid crystals (PDLCs) have been commonly used so far. However, a precise control of the light diffusion distribution of conventional PDLC has been difficult due to the random polymer network structure, which results in the low light utilization efficiency. On the other hand, reverse-mode PDLCs with homogeneously aligned molecules can anisotropically diffuse light. The reverse-mode PDLC, however, has polarization dependency in the haze value due to homogeneously aligned molecules, which also results in the low light utilization efficiency. Therefore, it is necessary to establish the optimization method of light diffusion distribution without the molecules alignment treatment, and we have proposed a novel PDLC with structure-controlled polymer network which was fabricated by the irradiation with uni-directionally diffused UV light. In this paper, we investigated the effect of the process temperature during UV irradiation on the internal structure and light diffusion distribution of the proposed PDLC. As a result, in case that the mixture during UV irradiation was in isotropic phase, we clarified that the structure-controlled PDLCs with alternating striped LCs/polymer pattern could be obtained because the mixture was sufficiently irradiated with uni-directionally diffused UV light. For the high haze, this structure-controlled PDLC should be fabricated as low temperature as possible with maintaining the mixture in isotropic phase so that the mixture was not a nano-scaled molecular mixing state. Also, this PDLC had no polarization dependency in the haze value and could electrically switch the light distribution pattern between anisotropic light diffusion and light transmission. From the above results, we concluded that the proposed PDLC could precisely control the light diffusion distribution, and realize the high light utilization efficiency.

In this paper, we examined the transfer method of fluororesin as the novel formation method of polymer wall in order to realize the lattice-shaped polymer walls without patterned light irradiation using photomask. We clarified that the transfer method was effective for formation of polymer wall structure on flexible substrate.

The authors have proposed a new type of flexible and printable 12GHz-band phase shifter using polymer actuator for the first time. Polymer bending actuator was used as a termination device of a reflection-type 3-dB, 90° hybrid coupler as the phase-shift control unit which controls the electrical length of the waveguide for microwave signals by the applied bias voltage. The microstrip line circuit of the device has been fabricated using low-cost screen printing method. Polymer bending actuator having three-layer stacking structure, in which an ionic liquid electrolyte layer is sandwiched with two conductive network composite layers, was formed by wet processes. The authors have confirmed that the phase shift could be controlled in analog by low driving voltages of 2-7 V for the actuator with a insertion loss of 2.73 dB. This phase shifter can be integrated with flexible patch antenna and the current flexible polymer electronics devices such as transistors.

We review the recent advances on strain and temperature sensing techniques based on multimodal interference in perfluorinated (PF) graded-index (GI) polymer optical fibers (POFs). First, we investigate their fundamental characteristics at 1300nm. When the core diameter is 62.5µm, we obtain strain and temperature sensitivities of -112pm/µε and +49.8nm/°C, the absolute values of which are, by simple calculation, approximately 13 and over 1800 times as large as those in silica GI multimode fibers, respectively. These ultra-high strain and temperature sensitivities probably originate from the unique PF polymer used as core material. Subsequently, we show that the temperature sensitivity (absolute value) is significantly enhanced with increasing temperature toward ∼70°C, which is close to the glass-transition temperature of the core polymer. When the core diameter is 62.5µm, the sensitivity at 72°C at 1300nm is 202nm/°C, which is approximately 26 times the value obtained at room temperature and >7000 times the highest value previously reported using a silica multimode fiber. Then, we develop a single-end-access configuration of this strain and temperature sensing system, which enhances the degree of freedom in embedding the sensors into structures. The light Fresnel-reflected at the distal open end of the POF is exploited. The obtained strain and temperature sensitivities are shown to be comparable to those in two-end-access configurations. Finally, we discuss the future prospects and give concluding remarks.

This paper introduces a formation method for 3-dimensional 6 ch.×6 ch. shuffling structures with graded-index (GI) circular core in a multimode polymer optical waveguide for optical printed circuit boards (OPCBs) using a unique photomask-free fabrication technique named the Mosquito method. The interchannel pitch of the fabricated waveguides is 250µm, where all the channels consist of both horizontal and vertical bending structures and the last 6 channels in parallel cross over the first 6 channels. We also report 3-dimensional S-shaped polymer waveguides. In the S-shaped waveguides, the first and last 6 channels with both horizontal and vertical core bending composing the above 3-dimensional shuffling waveguide are separated, in order to evaluate the effect of over-crossing on the loss. It is experimentally confirmed that there is no excess insertion loss due to the shuffling structure in the 3-D shuffling waveguide. The evaluated crosstalk of the 3-D shuffling waveguide is lower than -30dB. The 3-D shuffling waveguide proposed in this paper will be a promising component to achieve high bandwidth density wiring for on-board optical interconnects.

We developed flexible liquid crystal devices using ultra-thin polyimide substrates and bonding polymer spacers, and discussed the effects of polymer spacer structure on the cell thickness uniformity of flexible LCDs. We clarified that the lattice-shaped polymer spacer is effective to stabilize the cell thickness by suppressing the flow of the liquid crystal during bending process.

We examined the novel aggregation control of the LC and monomer during formation of the polymer walls from a LC/monomer mixture in order to suppress the presence of the residual monomers and polymer networks in the pixel areas. The method is utilization of the differing wettabilities among LC and monomer molecules on a substrate surface. We patterned a substrate surface with a fluororesin and a polyimide film, and promoted phase separation of the LC and monomer by cooling process. This resulted in the LC and monomer aggregates primarily existing in the pixel areas and non-pixel areas, respectively. Moreover, the polymer-walls structure which was formed in this method partitioned into individual pixels in a lattice region and prevented the LC from flowing. This polymer-walls formation technique will be useful for developing high-quality flexible LCDs.

We integrate a pressure sensing capacitor and a low operation voltage OFET to develop a pressure sensor. The OFET was used as a readout device and an external pressure was loaded on the sensing capacitor. The OFET operates at less than 5 V and the change in the drain current in response to the pressure load (100 kPa) is two orders of magnitude.

Thin films of vinyl derivatives of naphthalene diimide were prepared by electron-assisted vapor deposition. Monomer materials of N, N'-bis(allyl)-naphthalene diimide (Allyl-NDI) and N,N'-bis(p-vinyl-benzyl)-naphthalene diimide (Sty-NDI) were newly synthesized for this purpose. Uniform films were obtained by vapor-depositing these materials, whereas spin-coating yielded nonuniform films. IR analysis suggested that Sty-NDI can be polymerized upon vapor deposition. An insoluble film of Sty-NDI was obtained by the electron-assisted vapor deposition. On the other hand, Allyl-NDI had lower reactivity for polymerization. It was concluded that Sty-NDI is a promising material for preparing thin films of vinyl polymer having naphthalene diimide units.

For the future medical diagnostics, high-sensitive, rapid, and cost effective biosensors to detect the biomarkers have been desired. In this study, the polymer-based two-dimensional photonic crystal (2D-PC) was fabricated using nanoimprint lithography (NIL) for biosensing application. In addition, for biosensing application, label-free detection of fibrinogen which is a biomarker to diagnose the chronic obstructive pulmonary disease (COPD) could be achieved using antigen-antibody reaction high-sensitively (detection limit: pg/ml order) and rapidly. Using this polymer-based 2D-PC, optical biosensor can be developed cost effectively. Furthermore, by using polymer as a base material for fabrication of 2D-PC, label-free detection of antigen-antibody reaction can be performed in visible region.