The gap states of tetratetracontane (C44H90; TTC), which is a model oligomer of polyethylene, was examined by using high-sensitivity UV photoemission spectroscopy (HS-UPS). The high sensitivity enabled us to directly observe the weak gap states distributed in the HOMO-LUMO gap from the valence band top to 3.0 eV below the vacuum level. On the basis of the density-of-states derived from UPS results, the tribocharging nature of polyethylene was discussed in comparison with our previous result for nylon-6,6 film.
Yuki YAMAGUCHI
Chiba University
Kohei SHIMIZU
Chiba University
Atsushi MATSUZAKI
Chiba University
Daisuke SANO
Chiba University
Tomoya SATO
Chiba University
Yuya TANAKA
Chiba University
Hisao ISHII
Chiba University
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Yuki YAMAGUCHI, Kohei SHIMIZU, Atsushi MATSUZAKI, Daisuke SANO, Tomoya SATO, Yuya TANAKA, Hisao ISHII, "Gap States of a Polyethylene Model Oligomer Observed by Using High-Sensitivity Ultraviolet Photoelectron Spectroscopy" in IEICE TRANSACTIONS on Electronics,
vol. E102-C, no. 2, pp. 168-171, February 2019, doi: 10.1587/transele.2018OMS0008.
Abstract: The gap states of tetratetracontane (C44H90; TTC), which is a model oligomer of polyethylene, was examined by using high-sensitivity UV photoemission spectroscopy (HS-UPS). The high sensitivity enabled us to directly observe the weak gap states distributed in the HOMO-LUMO gap from the valence band top to 3.0 eV below the vacuum level. On the basis of the density-of-states derived from UPS results, the tribocharging nature of polyethylene was discussed in comparison with our previous result for nylon-6,6 film.
URL: https://global.ieice.org/en_transactions/electronics/10.1587/transele.2018OMS0008/_p
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@ARTICLE{e102-c_2_168,
author={Yuki YAMAGUCHI, Kohei SHIMIZU, Atsushi MATSUZAKI, Daisuke SANO, Tomoya SATO, Yuya TANAKA, Hisao ISHII, },
journal={IEICE TRANSACTIONS on Electronics},
title={Gap States of a Polyethylene Model Oligomer Observed by Using High-Sensitivity Ultraviolet Photoelectron Spectroscopy},
year={2019},
volume={E102-C},
number={2},
pages={168-171},
abstract={The gap states of tetratetracontane (C44H90; TTC), which is a model oligomer of polyethylene, was examined by using high-sensitivity UV photoemission spectroscopy (HS-UPS). The high sensitivity enabled us to directly observe the weak gap states distributed in the HOMO-LUMO gap from the valence band top to 3.0 eV below the vacuum level. On the basis of the density-of-states derived from UPS results, the tribocharging nature of polyethylene was discussed in comparison with our previous result for nylon-6,6 film.},
keywords={},
doi={10.1587/transele.2018OMS0008},
ISSN={1745-1353},
month={February},}
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TY - JOUR
TI - Gap States of a Polyethylene Model Oligomer Observed by Using High-Sensitivity Ultraviolet Photoelectron Spectroscopy
T2 - IEICE TRANSACTIONS on Electronics
SP - 168
EP - 171
AU - Yuki YAMAGUCHI
AU - Kohei SHIMIZU
AU - Atsushi MATSUZAKI
AU - Daisuke SANO
AU - Tomoya SATO
AU - Yuya TANAKA
AU - Hisao ISHII
PY - 2019
DO - 10.1587/transele.2018OMS0008
JO - IEICE TRANSACTIONS on Electronics
SN - 1745-1353
VL - E102-C
IS - 2
JA - IEICE TRANSACTIONS on Electronics
Y1 - February 2019
AB - The gap states of tetratetracontane (C44H90; TTC), which is a model oligomer of polyethylene, was examined by using high-sensitivity UV photoemission spectroscopy (HS-UPS). The high sensitivity enabled us to directly observe the weak gap states distributed in the HOMO-LUMO gap from the valence band top to 3.0 eV below the vacuum level. On the basis of the density-of-states derived from UPS results, the tribocharging nature of polyethylene was discussed in comparison with our previous result for nylon-6,6 film.
ER -