In this paper, we have investigated the characteristics of PdYb-silicide layer formed by the silicidation of Pd/Yb/n-Si(100) stacked structures for the first time. Pd (12-20 nm)/Yb (0-8 nm) stacked layers were deposited on n-Si(100) substrates by the RF magnetron sputtering at room temperature. Then, 10 nm-thick HfN encapsulating layer was deposited at room temperature. Next, silicidation was carried out by the RTA at 500°C/1 min in N2 followed by the selective etching. From the J-V characteristics of fabricated Schottky diode, Schottky barrier height (SBH) for electron was reduced from 0.73 eV of Pd2Si to 0.4 eV of PdYb-silicide in case the Pd/Yb thicknesses were 14/6 nm, respectively.

We have investigated PtHf silicide formation utilizing a developed PtHf-alloy target to realize low contact resistivity for the first time. A 20 nm-thick PtHf-alloy thin film was deposited on the n-Si(100) by RF magnetron sputtering at room temperature. Then, silicidation was carried out by rapid thermal annealing (RTA) system at 450-600°C/5 min in N2/4.9%H2 ambient. The PtHf-alloy silcide, PtHfSi, layers were successfully formed, and the Schottky barrier height (SBH) for electron of 0.45 eV was obtained by 450°C silicidation. Furthermore, low contact resistivity was achieved for fabricated PtHSi such as 8.4x10-8 Ωcm2 evaluated by cross-bridge Kelvin resistor (CBKR) method.