Lead bromide-based perovskite organic-inorganic quantum-well films incorporated polycyclic aromatic chromophores into the organic layer (in other words, hybrid quantum-wells combined lead bromide semiconductor and organic semiconductors) were prepared by use of the spin-coating technique from the DMF solution in which PbBr2 and alkyl ammonium bromides which were linked polycyclic aromatics, pyrene, phenanthrene, and anthracene. When the pyrene-linked methyl ammonium bromide, which has a relatively small molecular cross-section with regard to the inorganic semiconductor plane, was employed, a lead bromide-based perovskite structure was successfully formed in the spin-coated films. When the phenanthrene-linked and anthracene-linked ammonium bromides, whose chromophore have large molecular cross-sections, were employed, lead bromide-based perovskite structures were not formed. However, the introduction of longer alkyl chains into the aromatics-linked ammonium bromides made it possible to form the perovskite structure.

We make a theoretical study about the laser-induced radiation force exerted on nano materials under a quantum mechanical resonance condition of electronic systems [1] confined in them. In our recent study, we have clarified that the remarkable effects of the electronic resonance appear in the radiation force on the small object whose size is much smaller than the light wavelength; (A) the acceleration on the object gets larger as the size decreases, (B) the peaks with less heat appear in the force spectra even under the resonance condition, (C) the peak position sensitively varies with the nanoscale-size changes. These are useful for the optical manipulation to precisely control the mechanical motions of nano materials. In this paper, toward the experiment to verify the above results, we discuss the dependence of the mechanical motion of nano objects on the width of the incident laser light, and on the diffusion and friction effects assuming that they are floating in the superfluid helium-4 with the cryogenic condition where the electronic resonance effects become conspicuous. The results of calculations show that the particular nano objects, whose resonance energy corresponds to the center frequency of incident laser, can move away from others over macroscopic distance beyond diffusion length. This means that we can observe the distribution of sizes and qualities of nano objects as a macroscopic spatial distribution of them if we prepare appropriate conditions of incident light. We call this new technique 'Nano Optical Chromatography (NOC).'

Charge carrier generation, transport, and exciton diffusion in f ac tris(2-phenylpyridine)iridium(III) Ir(ppy)3 doped in 4,4'-N,N'-dicarbazole-biphenel (CBP) thin films, an emissive layer of green electrophosphorescent devices, have been studied in terms of time-of-flight (TOF) transient photocurrent, steady-state photocurrent and time-resolved photoluminescence (PL) spectroscopies. It is found that the excitation energy rapidly transfer from CBP to Ir(ppy)3, and that the charge carriers are generated on Ir(ppy)3 sites. With increasing Ir(ppy)3 concentration, the electron drift mobility is slightly decreased, while the hole transit signals become unobservable. The electron and hole transport properties of Ir(ppy)3 doped CBP thin films result from the energy levels of the lowest unoccupied molecular orbital and the highest occupied molecular orbital of Ir(ppy)3 with respect to those of CBP. From steady-state photocurrent measurement, the diffusion lengths of 3.5% and 7.0% Ir(ppy)3 doped CBP thin films are determined to be 21 nm and 50 nm, respectively.

We demonstrate a large nonlinear optical response of GaAs thin films using degenerate four-wave mixing (DFWM) with picosecond pulses. The obtained DFWM signal is thickness-dependent and peaks at around 110 nm. The nonlocal theory fully explains these results.

Excitonic optical properties of GaN homoepitaxial layers have been studied by means of magneto-luminescence and time-resolved luminescence spectroscopy. The luminescence lines due to the radiative recombination of excitons bound to neutral donors and acceptors have been measured under magnetic field up to 8 T, which was aligned perpendicular and parallel to the hexagonal c-axis. Under the magnetic field aligned perpendicular to the hexagonal c-axis, both the donor- and acceptor-bound-exciton lines clearly split into two components, which originated from the Zeeman splitting. The effective g-factors for both the donor- and acceptor-bound excitons were estimated to be 2.02 and 2.47, respectively. Under the magnetic field aligned parallel to the hexagonal c-axis, slight broadening of the bound-exciton lines was observed and the Zeeman splitting was too small to be detected. On the other hand, the diamagnetic shift for both the donor- and acceptor-bound-exciton luminescence lines was observed under the magnetic field aligned both perpendicular and parallel to the hexagonal c-axis. It was found that the diamagnetic shift of the donor-bound exciton was smaller than that of the acceptor-bound exciton. Furthermore, recombination dynamics of excitonic transitions was measured under high-density excitation. An excitation-density-dependent transition of the dominant radiative recombination process from donor-bound excitons to biexcitons was clearly observed in the temporal behavior. In addition, double-exponential decay of biexciton luminescence was observed, which is one of the characteristics of biexciton luminescence at high excitation densities.

The dipole-dipole interaction among excitons is shown to give rise to an intrinsic nonlinearity, which yields a localized mode in a forbidden band, providing a coherent state for quantum computation. Employing this mode, a quantum XOR (exclusive OR) gate is proposed. A block structure of quantum dot arrays is also proposed, to implement quantum circuits comprising the quantum XOR gates for computation.

Optical recording has been performed successfully by the preirradiation of light upon the precursor of poly (arylene vinylene) conducting polymers such as poly (p-phenylene vinylene) (PPV) and poly (1,4-naphthalene vinylene) (PNV) and subsequent thermal treatment. The effect has been tentatively interpreted in terms of the deterioration of the irradiated area of the precursor polymer in which polymerization is suppressed. Furthermore, an orange electroluminescent (EL) diode utilizing PNV has been demonstrated for the first time and the EL properties of PNV are discussed in comparison with those of EL diode utilizing PPV. The EL emission of these two devices are discussed in terms of radiative recombination of the singlet polaron exciton formed by the injection of electrons and holes, the difference of effective conjugation length and the interchain transfer of polaron excitons.

The Cooper pairing interaction in high Tc oxide superconductor is discussed in terms of an empirical expression; TcDexp[1/g], gcωo which was derived in our previous investigation. The dual character of this expression consisting of the phonon Debye temperature D and electronic excitation ωo in the mid-infrared region can be interpreted on the basis of the phonon-assisted mechanism on carrier conduction and the electronic excitation. A tunneling spectrum here presented shows certain evidence of the phonon contribution. The characteristics of the long range superconductive proximity phenomena recently reported are also may be interpreted by this mechanism.

The nonlinear optical properties of organics with unsaturated bonds were compared with those of inorganics including semiconductors and dielectrics. Because of the mesomeric effect, namely quantum mechanical resonance effect among configurations, aromatic molecules and polymers have larger optical nonlinear parameters defined as δ(n)=X(n)/(X(l))n both for the second (n=2) and third-order (n=3) nonlinearities. Experimental results of ultrafast nonlinear response of conjugated polymers, especially polydiacetylenes, were described and a model is proposed to explain the relaxation processes of photoexcitations in the conjugated polymers. Applying the model constructed on the basis of the extensive experimental study, we propose model polymers to obtain ultrafast resonant optical nonlinearity.