Graphene has been expected as an alternative material for copper interconnects in which resistance increases and reliability deteriorates in nanoscale. While the principle advantages are verified by simulations and experiments, they have not been put into practical use due to the immaturity of the manufacturing process leading to mass production. On the other hand, recent steady progress in the fabrication process has increased the possibility of practical application. In this paper, I will review the recent advances and the latest prospects for conductor applications of graphene centered on interconnects. The possibility of further application utilizing the unique characteristics of graphene is discussed.

In this study, we devised a biofuel cell (BFC) by impregnating sheet-like cellulose nanofiber (CNF) with liquid fuel (fructose) and sandwiching it with the electrodes, making the structure simple and compact. CNF was considered as a suitable material for BFC because it is biocompatible, has a large specific surface area, and exhibits excellent properties as a catalyst and an adsorbent. In this BFC device, graphene-coated carbon fiber woven cloth (GCFC) was used as the material for preparing the electrodes, and the amount of enzyme modification on the surface of each electrode was enhanced. Further, as the distance between the electrodes was same as the thickness of the sheet-shaped CNF, it facilitated the exchange of protons between the electrodes. Moreover, the cathode, which requires an oxidation reaction, was exposed to the atmosphere to enhance the oxygen uptake. The maximum power density of the CNF-type BFC was recorded as 114.5 µW/cm2 at a voltage of 293 mV. This is more than 1.5 times higher than that of the liquid-fuel-type BFC. When measured after 24 h, the maximum power density was recorded as 44.9 µW/cm2 at 236 mV, and the output was maintained at 39% of that observed at the beginning of the measurement. However, it is not the case with general BFCs, where the power generation after 24 h is less than 5%. Therefore, the CNF-type BFCs have a longer lifespan and are fuel efficient.

Improvement of output and lifetime is a problem for biofuel cells. A structure was adopted in which gelation mixed with agarose and fuel (fructose) was sandwiched by electrodes made of graphene-coated carbon fiber. The electrode surface not contacting the gel was exposed to air. In addition, grooves were added to the gel surface to further increase the oxygen supply. The power density of the fuel cell was examined in terms of the electrode area exposed to air. The output increased almost in proportion to the area of the electrode exposed to air. Optimization of the concentration of fuel, gel, and the amount of enzyme at the cathode were also examined. The maximum power density in the proposed system was approximately 121μW/cm2, an enhancement of approximately 2.5 times that in the case of using liquid fuel. For the power density after 24h, the fuel gel was superior to the fuel liquid.

Crystalline GaN films can be grown even on amorphous substrates with the use of graphene buffer layers by pulsed sputtering deposition (PSD). The graphene buffer layers allowed us to grow highly c-axis-oriented GaN films at low substrate temperatures. Full-color GaN-based LEDs can be fabricated on the GaN/graphene structures and they are operated successfully. This indicates that the present technique is promising for future large-area light-emitting displays on amorphous substrates.

Effects of electron beam irradiation at 15 keV on graphene are investigated by optical and electron characterization using Raman and two-terminal resistance measurement and photoconductivity measurement. In Raman spectra, increase of defects in D-peak to G-peak ratio by increase of electron irradiation by 70 mC/cm2 was found. Resistance of graphene showed an increase after the irradiation. Rather sensitive change was found in photoconductivity of irradiated graphene under ultra-violet (UV) illumination, suggesting irradiation induced defects affect a photoconductivity properties of the graphene.

We investigate the origin of non-ideal transfer characteristics in graphene-based three-branch nano-junction (TBJ) devices. Fabricated graphene TBJs often show asymmetric nonlinear voltage transfer characteristic, although symmetric one should appear ideally. A simple model considering the contact resistances in two input electrodes is deduced and it suggests that the non-ideal characteristic arises from inequality of the metal-graphene contact resistances in the inputs. We fabricate a graphene TBJ device with electrically equal contacts by optimizing the contact formation process and almost ideal nonlinear characteristic was successfully demonstrated.

The numerical dispersibility measurement system was fabricated based on optical transparency to objectively evaluate undetectable dispersibility by naked eyes. The small deference of dispersibility and the dispersibility behaviors were simultaneously elucidated by the system. The abundance of octadecyl groups was also discussed from the result of dispersibility behaviors. The objective numerical evaluation is needed for precise analysis of dispersibility with respect to graphene, graphene derivatives and graphene related materials.

Graphene is attracting attention in electrical and optical research fields recently. We measured the optical absorption characteristics and polarization dependence of single-layer graphene (SLG) on sub-micrometer Si waveguide. The results for graphene lengths ranging from 2.5 to 200 $mu$ m reveal that the optical absorption by graphene is 0.09 dB/$mu$ m with the TE mode and 0.05 dB/$mu$ m with the TM mode. The absorption in the TE mode is 1.8 times higher than that in the TM mode. An optical spectrum, theoretical analysis and Raman spectrum indicate that surface-plasmon polaritons in graphene support TM mode light propagation.

We investigated oxidation time dependence of graphene oxide employing modified Hummer method by dynamic light scattering. Oxidation reaction proceeded rapidly within about 24 hours, and was saturated. It is suggested that graphene oxides were not able to freely fragment. This implies that the oxidation reactions occur at the limited sites.

We have investigated the effect of deoxyribonucleic acid (DNA) adsorption on a graphene field-effect-transistor (FET) device. We have used graphene which is grown on a Ni substrate by chemical vapour deposition. The Raman spectra of our graphene indicate its high quality, and also show that it consists of only a few layers. The current-voltage characteristics of our bare graphene strip FET show a hole conduction behavior, and the gate sensitivity of 0.0034 µA/V, which is reasonable with the size of the strip (510 µm2). After the adsorption of 30 base pairs single-stranded poly (dT) DNA molecules, the conductance and gate operation of the graphene FET exhibit almost 11% and 18% decrease from those of the bare graphene FET device. The observed change may suggest a large sensitivity for a small enough (nm size) graphene strip with larger semiconducting property.