The thin film organic photovoltaic cells (OPVs) using organic semiconductors are inferior to oxgen-resistance and water-resistance, and the OPVs have a drawback that the photoelectric conversion efficiency (η) is low. For high efficiency of the OPVs, control of bulk heterojunction (BHJ) structure in the active layer is demanded. Therefore, it is thought that we can control the BHJ structure easily if we can bring a change in the aggregated structure and the crystallinity of the BHJ structure by introducing the third component that is different from the organic semiconductor into the activity layer. In this study, we introduced peptide consisting of phenylalanine of 2 molecules into the active layer prepared by poor solvent addition effect for the organic thin film solar cells and intended to try high efficiency of the organic thin film solar cells and examined the electrochemistry characteristic of the cells.

This paper presents a thin, compact beacon transmitter operating without needing battery replacement by using a photovoltaic (PV) film harvester. The beacon is formed of a power-control circuit (PCC) that can monitor small amounts of power from the harvester and properly control mode switching at low-power consumption. This leads to the realization of a maintenance-free beacon requiring no battery replacement. The beacon prototype is 55×20×2 mm in size and has a PV cell of 3 cm2. It allows a start-up operation from just 44-lux illuminance. The PV area required for the operation can be 1.7 times smaller than that of conventional beacons, thanks to the current saving with appropriate sequential control of the PCC. Since the beacon makes operation possible in emergency stairs, underground passages and other dark places, the application field for Internet of things (IoT) services can be expanded. Furthermore, a beacon equipped with a secondary battery (BSB: Beacon with Secondary Battery) can be configured by adding a charge-discharge power monitoring circuit. The BSB transmits an advertising packet during the daytime while charging surplus power, and works using the stored power during the night; this results in a continuous operation for one week with one transmission every 3 seconds even at 0-lux illuminance. Without developing a new radiofrequency chip or module, commercial low-power devices can be easily adjusted depending on the application by adding appropriate power-control circuits. We are convinced that this design scheme will be effective as a rapid design proposal for IoT services.

An optical intensity distribution under light irradiation in the organic photovoltaic cell affects the absorbance of the active layer, which determines the photovoltaic performance. In this research, we evaluated the optimum thickness of the organic active layer with poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl)] and [6,6]-phenyl C71-butyric acid methyl ester. The spectral response of external quantum efficiency was good agreement with the simulated optical intensity distribution within a device stack as a function of the position and the wavelength. As a result, the highest photoconversion efficiency of 10.1% was achieved for the inverted device structure.

Efficiency of the photovoltaic-assisted UHF CMOS rectifier, which is one example realization of the synergistic ambient energy harvesting concept, has been improved by symmetric PV cell structure. Balanced biasing for the n-channel and p-channel diode-connected MOSFETs realized by the symmetric PV cells effectively compensates Vths and prevents useless leakage current, resulting in the improved efficiency of the rectifier under low input power conditions. In addition, by extending the balanced biasing concept, output-voltage-boosted PV cell structure was proposed and found to be effective for further improving the efficiency of the rectifier. As a result, under a typical indoor lighting condition of 300lx, power conversion efficiency of 25.4% was achieved at -20dBm of 920MHz RF input and 47kΩ output loading conditions, being 3.6 times larger than a conventional rectifier without PV assistance.

We have optimized and evaluated organic thin-film solar cell devices with a structure of graded junction. The graded junction consisting of donor and accepter materials was fabricated by varying the deposition rates of both materials with a continuous grading, using two evaporation sources of cupper phthalocyanine and fullerene as p- and n-type materials, respectively. By evaluating device characteristics, optimized device structure ITO/CuPc (10 nm)/graded layer (35 nm)/C60 (15 nm)/BCP (10 nm)/Ag (100 nm) with an efficiency of 1.36% was obtained. In the structure, short-circuit current density was the largest and existence of larger voltage dependence in current density was observed. In addition, we have measured temperature dependences of current density versus voltage characteristics in the graded organic solar cell under illumination. The carrier extraction was enhanced by changing voltage possibly due to the internal electric field of the graded junction.

This paper introduces the basics of energy harvesters and demonstrates two specific vibratory-type energy harvesters developed at the University of Hyogo. The fabrication and evaluation results of the vibratory-type energy harvesters, which employ electrostatic and electromagnetic mechanisms, are described. The aim of developing these devices is to realize a power source for an autonomous human monitoring system. The results of harvesting from actual human activities obtained using a data logger are also described. Moreover, challenges in the power management of electronic circuitry used for energy harvesting are briefly discussed.

We demonstrated the reduced surface roughness of poly (3-hexylthiophene) (P3HT):(6,6)-phenyl-C61-butyric acid methyl ester (PCBM) thin films with different ratios fabricated by the electrospray deposition (ESD) method. Aggregated structures were observed at the lower voltage, and the uniformity became bad at the higher voltage. Anyway, the minimum root mean square (RMS) roughness was 1.46 nm by optimizing the applied voltage.

We succeeded to fabricate p-n heterojunction and bulkheterojunction small-molecular-weight organic thin-film solar cells by combination of dry (p-type = zinc phthalocyanine, n-type = fullerene) and wet (p-type = tetra-tert-butyl zinc phthalocyanine, n-type = [6,6]-phenyl-C61-buteric acid methyl ester) processes. Relationship between morphologies of semiconducting layers and photovoltaic properties was investigated. The p-n heterojunction organic thin-film solar cells based on dry process, where surface roughness was approximately 2 nm, showed the highest power conversion efficiency of 1.3% in this paper.

We fabricated organic p-n heterojunction, p-i-n heterojunction and all-i-layer photovoltaic cells of a zinc phthalocyanine (ZnPc)/1:1 codeposition (ZnPc:C60)/C60 structure with Al cathode. We investigated the effects of the device structure and the cathode material on the photovoltaic properties. The thickness of the i-layer was changed as 0 nm (= p-n heterojunction), 10 nm (= p-i-n heterojunction) or 50 nm (= all-i-layer) with the total thickness of 50 nm. We also changed cathode materials from Al to low-workfunction Mg:Ag electrode. Photovoltaic properties, i.e., short-circuit current density, fill factor and power conversion efficiency, were strongly influenced by the device structure and cathode material. Finally, the power conversion efficiency showed a maximum (1.5%) with the p-i-n structure and a Mg:Ag cathode under Air Mass 1.5 global solar conditions.