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Influences of Magnesium and Zinc Contaminations on Dielectric Breakdown Strength of MOS Capacitors

Makoto TAKIYAMA, Susumu OHTSUKA, Tadashi SAKON, Masaharu TACHIMORI

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Summary :

The dielectric breakdown strength of thermally grown silicon dioxide films was studied for MOS capacitors fabricated on silicon wafers that were intentionally contaminated with magnesium and zinc. Most of magnesium was detected in the oxide film after oxidation. Zinc, some of which evaporated from the surface of wafers, was detected only in the oxide film. The mechanism of the dielectric degradation is dominated by formation of metal silicates, such as Mg2SiO4 (Forsterite) and Zn2SiO4 (Wilemite). The formation of metal silicates has no influence on the generation lifetime of minority carriers, however, it provides the flat-band voltage shift less than 0.3 eV, and forces to increase the density of deep surface states with the zinc contamination.

Publication
IEICE TRANSACTIONS on Electronics Vol.E77-C No.3 pp.464-472
Publication Date
1994/03/25
Publicized
Online ISSN
DOI
Type of Manuscript
Special Section PAPER (Special Issue on Quarter Micron Si Device and Process Technologies)
Category
Process Technology

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